Hide
Show all
Email this article 
Turmeric (Curcuma longa) Extract Characterization for Corrosion Inhibitor using Microwave-Assisted Extraction
Abstract
Metallic corrosion, the deterioration process induced by the interaction between metals and corrosive environments, poses a significant challenge to material integrity and longevity. Corrosion inhibitors have been identified as an effective approach among various mitigation strategies. Natural extracts, such as those derived from turmeric/Curcuma longa, have garnered attention for their potential as eco-friendly corrosion inhibitors. This study endeavors to extract, characterize, and evaluate turmeric extract's efficacy as a corrosion inhibitor within a 30% acetic acid solution. Employing microwave-assisted extraction with a 96% ethanol solvent facilitated the isolation of the extract, which was subsequently subjected to qualitative analysis through phytochemical screenings and Gas Chromatography-Mass Spectrometry (GC-MS). These analyses confirmed the presence of antioxidative phytochemicals, including alkaloids, terpenoids, turmeronoids, curcumin, sesquiterpenoids, and phenols. The corrosion inhibitory properties of turmeric extract were assessed via immersion and flow loop experiments, revealing a notable reduction in corrosion rates—from 0.1540 mm/year to 0.0801 mm/year in immersion tests and from 5.3747 mm/year to 2.9369 mm/year in flow loop tests. Such outcomes underscore turmeric extract's potential as a viable corrosion inhibitor, attributed primarily to the chemical interactions facilitated by curcumin's phenolic and carbonyl groups with the metal surface, thereby enhancing protective efficacy. The inhibitor efficiency was quantified at 47.9743% and 45.3565% for immersion and flow loop tests, highlighting the extract's substantial inhibitory performance.
Keywords
Full Text:
PDFReferences
[1] G. Palanisamy, “Corrosion Inhibitors.”, IntechOpen, 2019, pp. 1-24,
doi: 10.5772/intechopen.80542
[2] A. Kadhim, A. A. Al-Amiery, R. Alazawi, M. K. S. Al-Ghezi, and R. H. Abass, “Corrosion inhibitors. A review,” International Journal of Corrosion and Scale Inhibition, vol. 10, no. 1, pp. 54–67, 2021,
doi: 10.17675/2305-6894-2021-10-1-3
[3] K. S. George and S. Nes, “Corrosion Science Section Corrosion-February 2007 Investigation of Carbon Dioxide Corrosion of Mild Steel in the Presence of Acetic Acid-Part 1: Basic Mechanisms,” Corrosion – The Journal of Science & Engineering, vol 63, no 2, pp. 178-186, 2007.
doi: 10.5006/1.3278342
[4] S. Cowlishaw, “Five Disasters Caused by Corrosion - PCI Magazina. 2021”
[5] T. E. Perez, “Corrosion in the oil and gas industry: An increasing challenge for materials,” JOM, vol. 65, no. 8, pp. 1033–1042, Aug. 2013,
doi: 10.1007/s11837-013-0675-3.
[6] C. Verma, E. E. Ebenso, M. A. Quraishi, and C. M. Hussain, “Recent developments in sustainable corrosion inhibitors: Design, performance and industrial scale applications,” Materials Advances, vol. 2, no. 12. Royal Society of Chemistry, pp. 3806–3850, Jun. 21, 2021.
doi: 10.1039/d0ma00681e.
[7] O. Gharbi, S. Thomas, C. Smith, and N. Birbilis, “Chromate replacement: what does the future hold?,” npj Materials Degradation, vol. 2, no. 1. Nature, Dec. 01, 2018.
doi: 10.1038/s41529-018-0034-5.
[8] D.Rahyudha, “Pengaruh Ph, Laju Aliran Fluida Dan Perbandingan Volume Inhibitor Pada Flow Loop System Terhadap Karakteristik Korosi Baja Karbon Rendah St-41 Di Lingkungan CH3COOH, Departemen Teknik Material, Institut Teknologi Sepuluh November, 2017”
[9] S. A. Umoren, M. T. Abdullahi, and M. M. Solomon, “An overview on the use of corrosion inhibitors for the corrosion control of Mg and its alloys in diverse media,” Journal of Materials Research and Technology, vol. 20. Elsevier Editora Ltda, pp. 2060–2093, Sep. 01, 2022.
doi: 10.1016/j.jmrt.2022.08.021.
[10] S. A. Umoren, “Polymers as Corrosion Inhibitors for Metals in Different Media-A Review,” The Open Corrosion Journal, vol 2, pp. 175-188, 2009.
doi: 10.2174/1876503300902010175
[11] J. De Damborenea, A. Conde, and M. A. Arenas, “Corrosion inhibition with rare earth metal compounds in aqueous solutions,” in Rare Earth-Based Corrosion Inhibitors, Elsevier Inc., 2014, pp. 84–116.
doi: 10.1533/9780857093585.84.
[12] P. D. Desai, C. B. Pawar, M. S. Avhad, and A. P. More, “Corrosion inhibitors for carbon steel: A review,” Vietnam Journal of Chemistry, vol. 61, no. 1. John Wiley and Sons Inc, pp. 15–42, Feb. 01, 2023.
doi: 10.1002/vjch.202200111.
[13] Y. Qiang, S. Zhang, B. Tan, and S. Chen, “Evaluation of Ginkgo leaf extract as an eco-friendly corrosion inhibitor of X70 steel in HCl solution,” Corros Sci, vol. 133, pp. 6–16, Apr. 2018,
doi: 10.1016/j.corsci.2018.01.008.
[14] Q. Wang et al., “Evaluation of Ficus tikoua leaves extract as an eco-friendly corrosion inhibitor for carbon steel in HCl media,” Bioelectrochemistry, vol. 128, pp. 49–55, Aug. 2019,
doi:10.1016/j.bioelechem.2019.03.001
[15] A. Mohammed Al-Fakih, M. Aziz, H. Mohd Sirat, A. Al-Fakih, M. Aziz, and H. Sirat, “Turmeric and ginger as green inhibitors of mild steel corrosion in acidic medium,” J. Mater. Environ. Sci, vol. 6, no. 5, pp. 1480–1487, 2015,
[16] E. A. Flores-Frias, V. Barba, M. A. Lucio-Garcia, R. Lopez-Cecenes, J. Porcayo-Calderon, and J. G. Gonzalez-Rodriguez, “Use of Curcuma and curcumin as a green corrosion inhibitors for carbon steel in sulfuric acid,” Int J Electrochem Sci, vol. 14, no. 6, pp. 5026–5041, Jun. 2016,
doi: 10.20964/2019.06.53.
[17] M. Nasibi, M. Mohammady, A. Ashrafi, A. A. D. Khalaji, M. Moshrefifar, and E. Rafiee, “Nanosized scale roughness and corrosion protection of mild steel in hydrochloric acid solution and in the presence of Turmeric (Curcuma Longa) Extract as a green corrosion inhibitor: FTIR, polarization, EIS, SEM, EDS, AFM studies, and neural network modeling,” J Adhes Sci Technol, vol. 28, no. 20, pp. 2001–2015, Oct. 2014, doi: 10.1080/01694243.2014.941053.
[18] M. B. Keivani, M. Edraki, I. M. Moghadam, and M. H. Fekri, “Turmeric extract as a biocompatible inhibitor of mild steel corrosion in 3.5% NaCl solution.” Iranian Chemical Communicaion, vol 7, pp. 146 – 159, 2019.
doi: 10.30473/icc.2018.42617.1486.
[19] K. S. Beena Kumari et al., “Curcumin As A Green Corrosion Inhibitor-A Review,” Journal of Advanced Scientific Research, vol 11, no 3, pp. 30-33. 2020.
[20] C. A. C. de Souza, M. Meira, L. O. de Assis, R. S. Barbosa, and S. Luna, “Effect of natural substances as antioxidants and as corrosion inhibitors of carbon steel on soybean biodiesel,” Materials Research, vol. 24, no. 5, 2021,
doi:10.1590/1980-5373-MR-2020-0234.
[21] A. Barzegar, “The role of electron-transfer and H-atom donation on the superb antioxidant activity and free radical reaction of curcumin,” Food Chem, vol. 135, no. 3, pp. 1369–1376, Dec. 2012,
doi: 10.1016/j.foodchem.2012.05.070.
[22] H. López-Salazar, B. H. Camacho-Díaz, M. L. Arenas Ocampo, and A. R. Jiménez-Aparicio, “Microwave-assisted Extraction of Functional Compounds from Plants: A Review,” Bioresources, vol. 18, no. 3, pp. 6614–6638, 2023,
doi:10.15376/biores.18.3.Lopez-Salazar.
[23] I. Narwanti and H. N. A. Afifah, “Conventional and Microwave-Assisted Synthesis of 4’-Bromochalchone Utilizing 4-Bromoacetophenone and Benzaldehyde as Starting Material in Alkaline Condition,” JKPK (Jurnal Kimia dan Pendidikan Kimia), vol. 7, no. 3, p. 346, Dec. 2022,
doi: 10.20961/jkpk.v7i3.66765.
[24] “Qomarudin., “Extraction of Pandanus Amaryllifiolus Roxb.: A Review of Methods and the Influencing Factors”, Qomarudin”, Advances in Food Science, Sustainable Agriculture and Agroindustrial Engineering, vol 6 no 1, pp. 72-87, 2023.
doi:10.21776/ub.afssaae.2023.006.01.7
[25] Z. Karami, Z. Emam-Djomeh, H. A. Mirzaee, M. Khomeiri, A. S. Mahoonak, and E. Aydani, “Optimization of microwave assisted extraction (MAE) and soxhlet extraction of phenolic compound from licorice root,” J Food Sci Technol, vol. 52, no. 6, pp. 3242–3253, Jun. 2015, doi: 10.1007/s13197-014-1384-9.
[26] H. Heriyanto, A. R. Permanasari, A. Wibisono, and S. G. Purnomoaji, “Control of aluminum corrosion in seawater environment by adding turmeric extract to the coating material,” in IOP Conference Series: Materials Science and Engineering, Institute of Physics Publishing, May 2020.
doi:10.1088/1757-899X/830/2/022017.
[27] F. Azzahra and T. Budiati, “pengaruh metode pengeringan dan pelarut ekstraksi terhadap rendemen dan kandungan kimia ekstrak daun alpukat (persea americana mill.) effects of drying method and solvents on yield and chemical content of avocado leaves extract (Persea americana Mill.),” Medical Sains, vol. 7, no. 1, 2022.
doi: 10.37874/ms.v7i1.
[28] A. Luviana et al., “Pengaruh Pelarut yang Digunakan terhadap Hasil Ekstraksi Kunyit (Curcuma Longa L.). Prosiding the 14th Industrial Research Workshop and National Seminar, vol 14, no 1,pp. 123 – 127, 2023. doi:10.35313/irwns.v14i1.5372 .
[29] U. Suhendar, N. F. Utami, Dr. Sutanto, and S. M. Nurdayanty, “Pengaruh Berbagai Metode Ekstraksi Pada Penentuan Kadar Flavonoid Ekstrak Etanol Daun Iler (Plectranthus scutellarioides),” FITOFARMAKA: Jurnal Ilmiah Farmasi, vol. 10, no. 1, pp. 76–83, Jun. 2020,
doi: 10.33751/jf.v10i1.2069.
[30] A. K. Popuri and B. Pagala, “Extraction of Curcumin From Turmeric Roots,” Int J Innov Res Stud, 2013, [Online]. Available: www.ijirs.com
[31] H. Heriyanto, A. R. Permanasari, A. Wibisono, and S. G. Purnomoaji, “Control of aluminum corrosion in seawater environment by adding turmeric extract to the coating material,” in IOP Conference Series: Materials Science and Engineering, Institute of Physics Publishing, May 2020.
doi:10.1088/1757-899X/830/2/022017.
[32] M. D. Ciuca and R. C. Racovita, “Curcumin: Overview of Extraction Methods, Health Benefits, and Encapsulation and Delivery Using Microemulsions and Nanoemulsions,” International Journal of Molecular Sciences, vol. 24, no. 10. Multidisciplinary Digital Publishing Institute (MDPI), May 01, 2023.
doi: 10.3390/ijms24108874.
[33] Q A’yun and A.N. Laily., “Analisis Fitokimia Daun Pepaya (Carica papaya L.) Di Balai Penelitian Tanaman Aneka Kacang dan Umbi, Kendalpayak, Malang”, Seminar Nasional Konservasi dan Pemanfaatan Sumber Daya Alam 2015, pp. 134-137, 2015.
[34] D. Parajuli et al., “Comparative Study of Corrosion Inhibition Efficacy of Alkaloid Extract of Artemesia vulgaris and Solanum tuberosum in Mild Steel Samples in 1 M Sulphuric Acid,” Electrochem, vol. 3, no. 3, pp. 416–433, Sep. 2022,
doi: 10.3390/electrochem3030029.
[35] H.-J. Li, W. Zhang, and Y.-C. Wu, “Anti-Corrosive Properties of Alkaloids on Metals,” in Alkaloids - Their Importance in Nature and Human Life, IntechOpen, 2019.
doi: 10.5772/intechopen.81749.
[36] Saputra, T.R and Ngatin, A. “Ekstraksi Daun Cocor Bebek Menggunakan Berbagai Pelarut Organik Sebagai Inhibitor Korosi Pada Lingkungan Asam Klorida”, Fullerene Journal of Chemisry, vol 4 no 1, pp. 21-27, 2019. doi: 10.37033/fjc.v4iq.50.
[37] A. H. Alamri, “Experimental and theoretical insights into the synergistic effect of iodide ions and 1-acetyl-3-thiosemicarbazide on the corrosion protection of c1018 carbon steel in 1 m hcl,” Materials, vol. 13, no. 21, pp. 1–17, Nov. 2020,
doi: 10.3390/ma13215013.
[38] S. A. Umoren and M. M. Solomon, “Synergistic corrosion inhibition effect of metal cations and mixtures of organic compounds: A Review,” Journal of Environmental Chemical Engineering, vol. 5, no. 1. Elsevier Ltd, Feb. 01, 2017.
doi: 10.1016/j.jece.2016.12.001.
[39] P. R. Roberge, Handbook of corrosion engineering. McGraw-Hill, 2000.
[40] R. L. De Paula et al, “Evaluation of the turmeric dye extraction residue in the formation of protective coating on fresh bananas (Musa acuminata cv. ‘Maçã’),” J Food Sci Technol, vol. 55, no. 8, pp. 3212–3220, Aug. 2018,
doi: 10.1007/s13197-018-3252-5.
[41] M. Ramdhani, et al., “Pengaruh Inhibitor Korosi Molibdat dan Kromat Terhadap Laju Korosi Baja Struktur (Baja Karbon ASTM A36) dengan Media Air Proses di Pabrik Pengolahan Pertambangan Tembaga” , Prosiding Seminar Nasional Tahunan Teknik Mesin (SNTTM), Universitas Hasanuddin, pp. 286-293, 2022.
[42] T. Hong, et al, “Study on corrosion inhibitor in large pipelines under multiphase flow using EIS.” Journal Corrosion Science, vol 44, pp 101-112, 2022.
doi: 10.1016/S0010-938X(01)00052-X.
[43] Y. Chen, et al., “Effects Of Multiphase Flow On Corrosion Inhibitor.” Corrosion99, 1999.
[44] H. Biora Putra et al, “Pemanfaatan Ekstrak Kulit Kakao Sebagai Aditif Cat Untuk Pengendalian Laju Korosi Pada Paku Konstruksi Kapal Kayu,” Jurnal Inovtek Polbeng, vol. 8, no. 1, pp. 52-58, 2018.
doi: 10.35314/ip.v8i1.272.
Refbacks
- There are currently no refbacks.
