Application of Nanocomposit Of Al2O3/Activated Carbon Prepared by Hydrothermal Process for Phenol Removal
Abstract
Nancomposite of Al2O3/activated carbon was prepared from the mixture of alumina oxide (Al2O3) and activated carbon from palm oil shell under the mixture of aquabidest and ethanol (1:1). The mixture was treated by hydrothermal process at 250 oC for 3 h. Resulted Al2O3/ activated carbon was characterized using SEM/EDX for studying the morphology structure of activated carbon and composite showing a like flower structure attached on the surface. The chemical compositions were 73.18%, oxygen 23.72%, aluminium 2.30%, dan silica 2.00%. The efficiency of composite was investigated for removal of phenol in aqueous solution. The maximum adsorption of phenol was obtained at pH 2, adsorbent weight 2 g, contact time 60 min and phenol concentration 100 ppm.
Keywords
Full Text:
PDFReferences
M. A. M. Abdallah, “The potential of different bio adsorbents for removing phenol from its aqueous solution”. Environmental Monitoring and Assessment, vol.185, no.8, pp,6495–6503,2013.
DOI: 10.1007/s10661-012-3041-y
V. A. Angelini, E. Agostini, M. I. Medin, & P. S. González, “Use of hairy roots extracts for 2,4-DCP removal and toxicity evaluation by Lactuca sativa test”, Environmental Science and Pollution Research. vol,21, no 4, pp2531–2539. 2014
DOI: 10.1007/s11356-013-2172-1
S. Slamet, R. Arbianti, & E. Marliana, "Pengolahan Limbah Cr(VI) dan Fenol dengan Fotokatalis Serbuk TiO2 DAN CuO/TiO2," Reaktor, vol. 11, no. 2, pp. 78-85, 2007.
DOI: 10.14710/reaktor.11.2.78-85
G. Bayramoglu, I. Gursel, Y. Tunali, & M. Y. Arica,” Biosorption of phenol and 2-chlorophenol by Funalia trogii pellets. Bioresour Technol, vol, 100,no 10 pp 2685-91.2009.
DOI: 10.1016/j.biortech.2008.12.042
B. H. Hameed & A. A. Rahman, “Removal of phenol from aqueous solutions by adsorption onto activated carbon prepared from biomass material”. J. Hazard Mater. Vol.160, no. 2, pp 576-81, 2008.
DOI: 10.1016/j.jhazmat.2008.03.028
M. Zazouli, D. Balarak, & Y. Mahdavi, “Application of azolla for 2-chlorophenol and 4-chrorophenol removal from aqueous solutions”. Iran J. Health Sci., vol.1, no.2, pp. 43-55, 2013.
DOI: 10.18869/acadpub.jhs.1.2.43
R. I. Yousef, B. El-Eswed, & A. H. Al-Muhtaseb, “Adsorption characteristics of natural zeolites as solid adsorbents for phenol removal from aqueous solutions: Kinetics, mechanism, and thermodynamics studies”. Chem Eng. J., vol.171, no.3, pp, 1143-9.2011.
DOI: 10.1016/j.cej.2011.05.012
Z. Liu & F. S. Zhang, “Removal of copper (II) and phenol from aqueous solution using porous carbons derived from hydrothermal chars”. Desalination vol. 267, no. 1, pp. 101-6,2011.
DOI: 10.1016/j.desal.2010.09.013
Allwar, M. Noor, & M. A. M. Nawi, “Textural Characteristic of Activated Carbons Prepared from Oil Palm Shells Activated with ZnCl2 and Pyrolisys Under Nitrogen and Carbon Dioxide”, Phys. Sci, vol. 19, no. 2, pp. 93-104. 2008.
M. M. Titirici & M. Antonietti, “Chemistry and Materials Options of Sustainable Carbon Materials Made by Hydrothermal Carbonization, Chem”, Soc, rev, vo.l 10, no. 1, pp. 26-29. 2010.
A. D. Eaton, L. S.Clesceri, A. E. Greenberg, & M. A. H. Franson, “Standard methods for the examination of water and wastewater”. Am Public Health Assoc, vol. 1015, pp. 49–51,2013.
B. Ismail, S. T. Hussain, & S. Akram., “Adsorption of methylene blue onto spinel magnesium aluminate nanoparticles: Adsorption isotherms, kinetic and thermodynamic studies”. Chemical Engineering Journal, vol 219 pp 395–402. 2013.
DOI: 10.1016/j.cej.2013.01.034
Allwar, Z .F. Halimah, & Y. Rizky, “Preparation and characterization of hydrothermal activated carbon from banana empty fruit bunch with ZnCl2 activated for removal od phenol in aqueous solution”, Asian J. of Applied Sciences, vol.11, no. 1 pp. 20-28,2018
D. Kim, K. Yoshikawa, & K. Y. Park, “Characteristics of biochar obtained by hydrothermal carbonization of cellulose for renewable energy”. Energies vol 8 no 12 pp 14040–14048.2015.
B. Abussaud, V. K. Gupta, & I. Khan, “Sorption of Phenol from Waters on Activated Carbon Impregnated with Iron Oxide, Aluminium Oxide, and Titanium Oxide”, Mol. Liq, vol 213 pp 351-359.2015.
Refbacks
- There are currently no refbacks.