Synthesis of Polystyrene Fiber Membranes Prepared by Electrospinning: Effect of AgNO3 on the Microstructure

Hanifah Setyaning Budi, Akmal Zulfi, Lia Dwi Setyaningsih, Muhammad Fahroji, Ratih Amalia, Julia Angel, Bagas Haqi Arrosyid, Gugus Handika, Kurniawan Eko Saputro, Alfian Noviyanto, Yulianto Agung Rezeki

Abstract

Polystyrene (PS) is commonly employed in insulation, packaging, filters, and medical equipment, with recent studies exploring its potential in fiber membrane production. The electrospinning technique is discussed to synthesize PS fiber membranes with high porosity and controllable diameter. Additionally, incorporating silver nitrate into PS composite fibers is explored for enhanced functionalities such as catalytic activity, high electrical conductivity, and antibacterial activity. However, PS composite fiber membranes with silver nitrate (AgNO3) metal variations are rarely observed. This research aims to modify the microstructure of PS fiber membranes produced using electrospinning by adding silver nitrate (AgNO3) with varying concentrations. PS-Ag fiber membranes are produced using N,N-dimethylformamide (DMF) solvent, which serves as a solvent and a reducing agent for Ag. The results show that the effect of Ag affected the diameter of the PS-Ag fiber membrane, with an average diameter of around 3.67 - 6.93 micrometers. Degradation occurred in these samples at a strong broadening peak near ~1300 cm-1 until ~1600 cm-1 from the Raman results. The FTIR results show that the wavelength of ~3500 cm-1 indicated the presence of OH. The presence of OH indicates that the PS-Ag fiber membrane has the potential for water filtration application

Keywords

electrospinning; fiber membranes; polystyrene; silver nitrate

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References

[1] K. H. Lee, H. Y. Kim, H. J. Bang, Y. H. Jung, and S. G. Lee, "The change of bead morphology formed on electrospun polystyrene fibers," Polymer (Guildf)., vol. 44, no. 14, pp. 4029–4034, 2003, doi: 10.1016/S0032-3861(03)00345-8.

[2] T. Uyar and F. Besenbacher, "Electrospinning of uniform polystyrene fibers: The effect of solvent conductivity," Polymer (Guildf)., vol. 49, no. 24, pp. 5336–5343, 2008, doi: 10.1016/j.polymer.2008.09.025.

[3] A. M. Youssef and M. S. Abdel-Aziz, "Preparation of Polystyrene Nanocomposites Based on Silver Nanoparticles Using Marine Bacterium for Packaging," Polym. - Plast. Technol. Eng., vol. 52, no. 6, pp. 607–613, 2013, doi: 10.1080/03602559.2012.762658.

[4] A. Rajak, D. A. Hapidin, F. Iskandar, M. M. Munir, and K. Khairurrijal, "Controlled morphology of electrospun nanofibers from waste expanded polystyrene for aerosol filtration," Nanotechnology, vol. 30, no. 42, 2019, doi: 10.1088/1361-6528/ab2e3b.

[5] M. Mostafa, N. G. Kandile, M. K. Mahmoud, and H. M. Ibrahim, "Synthesis and characterization of polystyrene with embedded silver nanoparticle nanofibers to utilize as antibacterial and wound healing biomaterial," Heliyon, vol. 8, no. 1, p. e08772, 2022, doi: 10.1016/j.heliyon.2022.e08772.

[6] L. W. McKeen, Plastics Used in Medical Devices. Elsevier Inc., 2014, doi: 10.1016/B978-0-323-22805-3.00003-7.

[7] T. Blachowicz and A. Ehrmann, "Recent developments in electrospun ZnO nanofibers: A short review," J. Eng. Fiber. Fabr., vol. 15, 2020, doi: 10.1177/1558925019899682.

[8] R. A. Sheldon and J. K. Kochi, Metal-Catalyzed Oxidations of Organic Compounds. Oxford: Elsevier Science, 1981, doi: https://doi.org/10.1016/B978-0-12-639380-4.X5001-5.

[9] S. Huan, Y. F. Zhao, M. M. Munir, H. Kang, W. S. Mustika, and K. Khairurrijal, "Effect of experimental parameters on morphological, mechanical and hydrophobic properties of electrospun polystyrene fibers," Materials (Basel). vol. 8, no. 5, pp. 2718–2734, 2015, doi: 10.3390/ma8052718.

[10] C. L. Casper, J. S. Stephens, N. G. Tassi, D. B. Chase, and J. F. Rabolt, "Controlling surface morphology of electrospun polystyrene fibers: Effect of humidity and molecular weight in the electrospinning process," Macromolecules, vol. 37, no. 2, pp. 573–578, 2004, doi: 10.1021/ma0351975.

[11] K. Jalaja, R. Sreehari, M. M. Munir, W. S. Mustika, and K. Khairurrijal, "Effective SERS detection using a flexible wiping substrate based on electrospun polystyrene nanofibers," Anal. Methods, vol. 9, no. 26, pp. 3998–4003, 2017, doi: 10.1039/c7ay00882a.

[12] R. Neppalli, Y. F. Zhao, M. M. Munir, H. Kang, W. S. Mustika, and K. Khairurrijal, "Polystyrene/TiO2 composite electrospun fibers as fillers for poly(butylene succinate-co-adipate): Structure, morphology, and properties," Eur. Polym. J., vol. 50, no. 1, pp. 78–86, 2014, doi: 10.1016/j.eurpolymj.2013.11.002.

[13] S. Hartati, Y. A. Rezeki, M. M. Munir, and K. Khairurrijal, "Synthesis of Electrospun PAN/TiO2/Ag Nanofibers Membrane As Potential Air Filtration Media with Photocatalytic Activity," ACS Omega, vol. 7, no. 12, pp. 10516–10525, 2022, doi: 10.1021/acsomega.2c00015.

[14] A. N. Putri and M. Munasir, "Review : Fabrikasi Membran Berbasis Nanofiber Dengan Metode Electrospinning," Inov. Fis. Indones., vol. 9, no. 2, pp. 47–55, 2020, doi: https://doi.org/10.26740/ifi.v9n2.p47-55.

[15] S. Sihn, R. Y. Kim, W. Huh, K. H. Lee, and A. K. Roy, "Improvement of damage resistance in laminated composites with electrospun nano-interlayers," Compos. Sci. Technol., vol. 68, no. 3–4, pp. 673–683, 2008, doi: 10.1016/j.compscitech.2007.09.015.

[16] P. J. Rivero, A. Iribarren, S. Larumbe, J. F. Palacio, and R. Rodríguez, "A comparative study of multifunctional coatings based on electrospun fibers with incorporated ZnO nanoparticles," Coatings, vol. 9, no. 6, 2019, doi: 10.3390/coatings9060367.

[17] B. M. Thamer, F. A. Al-aizari, H. S. Abdo, and A. M. Al-Enizi, "Activated carbon-decorated electrospun polystyrene fibers for highly efficient removal of hazardous crystal violet dye from water," Colloids Surfaces A Physicochem. Eng. Asp., vol. 688, no. March, p. 133612, 2024, doi: 10.1016/j.colsurfa.2024.1336121.

[18] S. Wanjale, M. M. Munir, W. S. Mustika, K. Khairurrijal, and H. Kang, "Surface tailored PS/TiO2 composite nanofiber membrane for copper removal from water," J. Colloid Interface Sci., vol. 469, pp. 31–37, 2016, doi: 10.1016/j.jcis.2016.01.054.

[19] J. Song, M. M. Munir, W. S. Mustika, K. Khairurrijal, and H. Kang, "Safe and effective Ag nanoparticles immobilized antimicrobial nano-nonwovens," Adv. Eng. Mater., vol. 14, no. 5, pp. 12–14, 2012, doi: 10.1002/adem.201180085.

[20] L. Wannatong, A. Sirivat, and P. Supaphol, "Effects of solvents on electrospun polymeric fibers: Preliminary study on polystyrene," Polym. Int., vol. 53, no. 11, pp. 1851–1859, 2004, doi: 10.1002/pi.1599.

[21] A. Kulkarni, V. A. Bambole, and P. A. Mahanwar, "Electrospinning of Polymers, Their Modeling and Applications," Polym. - Plast. Technol. Eng., vol. 49, no. 5, pp. 427–441, 2010, doi: 10.1080/03602550903414019.

[22] A. Zulfi, M. M. Munir, W. S. Mustika, K. Khairurrijal, and H. Kang, "Air filtration media from electrospun waste high-impact polystyrene fiber membrane," Mater. Res. Express, vol. 5, no. 3, p. 035049, 2018, doi: 10.1088/2053-1591/aab6ef.

[23] G. Prahasti, D. Edikresnha, Y. A. Rezeki, M. M. Munir, and K. Khairurrijal, "The Synthesis and Characterization of Composite Electrospun Fibers of Polyvinylpyrrolidone and Shell Extract of Melinjo (Gnetum gnemon L.)," Mater. Today Proc., vol. 13, pp. 187–192, 2019, doi: 10.1016/j.matpr.2019.03.212.

[24] D. Mustikasari, Y. A. Rezeki, M. M. Munir, H. Rachmawati, and K. Khairurrijal, "Turmeric extract-loaded polyvinylpyrrolidone spherical submicron particles produced using electrohydrodynamic atomization: their physicochemical properties and antioxidant activity," Mater. Res. Express, vol. 6, no. 8, p. 085415, 2019, doi: 10.1088/2053-1591/ab272a.

[25] A. Zulfi, Y. A. Rezeki, D. Edikresnha, M. M. Munir, and K. Khairurrijal, "Synthesis of Fibers and Particles from Polyvinyl Chloride (PVC) Waste Using Electrospinning," IOP Conf. Ser. Mater. Sci. Eng., vol. 367, no. 1, 2018, doi: 10.1088/1757-899X/367/1/012014.

[26] A. Zulfi, D. A. Hapidin, M. M. Munir, F. Iskandar, and K. Khairurrijal, "The synthesis of nanofiber membranes from acrylonitrile butadiene styrene (ABS) waste using electrospinning for use as air filtration media," RSC Adv., vol. 9, no. 53, pp. 30741–30751, 2019, doi: 10.1039/c9ra04877d.

[27] Y. A. Rezeki, N. Wahyuni, M. M. Munir, and K. Khairurrijal, "Synthesis of polyvinylpyrrolidone/mangosteen pericarp extract (MPE) fibered particles using electrospray," J. Phys. Conf. Ser., vol. 1282, p. 012033, 2019, doi: 10.1088/1742-6596/1282/1/012033.

[28] M. Mazilu, A. C. De Luca, A. Riches, C. S. Herrington, and K. Dholakia, "Optimal algorithm for fluorescence suppression of modulated Raman spectroscopy," Opt. Express, vol. 18, no. 11, p. 11382, 2010, doi: 10.1364/oe.18.011382.

[29] M. Wang, J. Wen, Y. Huang, and P. Hu, "Selective Degradation of Styrene-Related Plastics Catalyzed by Iron under Visible Light**," ChemSusChem, vol. 14, no. 22, pp. 5049–5056, 2021, doi: 10.1002/cssc.202101762.

[30] I. A. Brezestean et al., "Silver Nanoparticle Films Obtained by Convective Self-Assembly for Surface-Enhanced Raman Spectroscopy Analyses of the Pesticides Thiabendazole and Endosulfan," Front. Chem., vol. 10, no. June, pp. 1–14, 2022, doi: 10.3389/fchem.2022.915337.

[31] R. S. Venkatachalam, F. J. Boerio, M. R. Carnevale, and P. G. Roth, "Degradation of polystyrene on silver substrates during surface-enhanced Raman scattering," Appl. Spectrosc., vol. 42, no. 7, pp. 1207–1213, 1988, doi: 10.1366/0003702884430056.

[32] J. A. Yabagi, M. I. Kimpa, M. N. Muhammad, S. Bin Rashid, E. Zaidi, and M. A. Agam, "The effect of gamma irradiation on chemical, morphology and optical properties of polystyrene nanosphere at various exposure times," IOP Conf. Ser. Mater. Sci. Eng., vol. 298, no. 1, 2018, doi: 10.1088/1757-899X/298/1/012004.

[33] R. Sarwono, "Pemanfaatan Kitin / Kitosan Sebagai Bahan Anti Mikroba," J. Kim. Terap. Indones., vol. 12, no. 1, pp. 32–38, 2010, doi: 10.14203/jkti.v12i1.150.

[34] A. Zulfi, D. A. Hapidin, C. Saputra, W. S. Mustika, M. M. Munir, and K. Khairurrijal, "The synthesis of fiber membranes from High-Impact Polystyrene (HIPS) Waste using needleless electrospinning as air filtration media," Mater. Today Proc., vol. 13, pp. 154–159, 2019, doi: 10.1016/j.matpr.2019.03.206.

[35] A. Zulfi, M. M. Munir, W. S. Mustika, K. Khairurrijal, H. Kang, "Air filtration media from electrospun waste high-impact polystyrene fiber membrane," Mater. Res. Express, vol. 5, no. 3, 2018, doi: 10.1088/2053-1591/aab6ef.



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