Ability Test of C-4-Methoxyphenyl-Calix[4]resorcinarene as An Inhibitor of Calcium Carbonate (CaCO3) Crust Growth at Various Concentration

Suryadi Budi Utomo, Lathifah Ramadhani, Kisti Makrifatul Hanifah, Zamira Zia’ul Huda, Elfi Susanti V.H, Sri Retno Dwi Ariani, Sri Mulyani, Muhammad Hizbul Wathon

Abstract

The primary objective of this study was to evaluate the capacity of C-4-methoxyphenyl-calix[4]resorcinarene in impeding the development of CaCO3 crust at varying concentrations of the inhibitor and different durations of contact. The research employed a seeded experimental approach using a 0.1 M CaCO3 growth solution maintained at 80 °C. The concentrations of C-4-methoxyphenyl-calix[4]resorcinarene introduced into the CaCO3 growth solution were 0, 5, 10, 20, and 40 ppm. The experimental procedure commenced with preparing crystal seeds, which is pivotal for gauging crystal growth rates. Results obtained from crystal weighing and morphological analysis through Scanning Electron Microscopy (SEM) indicated that C-4-methoxyphenyl-calix[4]resorcinarene effectively impeded the pace of CaCO3 scaling. The inhibitory efficacy of C-4-methoxyphenyl-calix[4]resorcinarene as a CaCO3 scaling inhibitor was contingent on well-regulated temperature during the heating phase. The inhibition effectiveness was positively correlated with the inhibitor's concentration; higher concentrations yielded superior suppression of CaCO3 scaling. Optimal scale reduction was observed at an inhibitor concentration of 10 ppm during a 20-minute contact period. These findings underscore the promising potential of C-4-methoxyphenyl-calix[4]resorcinarene as a viable inhibitor for mitigating scaling growth rates in various industrial fluid systems and related contexts.

Keywords

C-4-methoxyphenyl-calix[4]resorcinarene; CaCO3 crust; scale growth inhibitor; Ca2+

Full Text:

PDF

References

[1] Suharso and Buhani, Penanggulangan Kerak, Yogyakarta: Graha Ilmu, 2015,

ISBN: 9786022625094.

[2] M. Syahri and B. Sugiharto, “Scale Treatment pada Pipa Distribusi Crude Oil Secara Kimiawi,” Prosiding Seminar Nasional Teknoin, 2008.

Google Scholar

[3] Y. Usmany, W.A. Putranto, A.P. Bayuseno, and S. Muryanto, “Crystallization of calcium carbonate (CaCO3) in a flowing system: Influence of Cu2+ additives on induction time and crystalline phase transformation,” AIP Conference Proceedings, vol. 172, 2016,

doi: 10.1063/1.4945547.

[4] A. Bhatia, “Cooling Water Problems and Solutions,” Continuing Education and Development. 2003.

Google Scholar

[5] A. S. Braga and Y. Filion, “The interplay of suspended sediment concentration, particle size, and fluid velocity on the rapid deposition of suspended iron oxide particles in PVC drinking water pipes,” Water Research X, vol.15, pp. 100143, 2022,

doi: 10.1016/j.wroa.2022.100143.

[6] M. Morita and O. Umezawa, “A Model of Scale Formation on Inner Carbon Steel Pipe Walls for Transporting Hot Spring Water,” Materials Transactions, vol.57, no. 9, pp. 1652-1659, 2016,

doi: 10.2320/matertrans.M2016105.

[7] M. Mpelwa and S. F. Tang, “State of the art of synthetic threshold scale inhibitors for mineral scaling in the petroleum industry: a review,” Pet. Sci., vol. 16, pp. 830-849, 2019,

doi: 10.1007/s12182-019-0299-5.

[8] Suharso, Buhani, and T. Suhartati, “Inhibition of calcium carbonate (CaCO3) scale formation by calix[4]resorcinarene compounds,” Desalination and Water Treatment, vol. 68, pp. 32-39, 2017,

doi: 10.5004/dwt.2017.20311.

[9] Suharso, Buhani, and L. Aprilia, “Influence of Calix[4]arene Derived Compound on Calcium Sulphate Scale Formation,” Asian Journal of Chemistry, vol. 26, no. 18, pp. 6155-6158, 2014,

doi: 10.14233/ajchem.2014.16899.

[10] S. B. Utomo, Jumina, D. Siswanta, Mustofa, and N. Kumar, “Synthesis of Thiomethylated Calix[4]resorcinarene Based on Fennel Oil via Chloromethylation,” Indo. J. Chem., vol. 11, no.1, pp.1-8, 2011,

doi: 10.22146/ijc.21411.

[11] S. B. Utomo, A. N. C. Saputro, and Y. Rinanto, “Functionalization of C-4-methoxyphenylcalix[4]resorcinarene with several ammonium compounds,” IOP Conf. Series: Material Science and Engineering, vol. 107, pp. 012042, 2016,

doi: 10.1088/1757-899X/107/1/012042.

[12] S. B. Utomo, Jumina, D. Siswanta, and Mustofa, “Kinetics and Equilibrium Model of Pb(II) and Cd(II) Adsorption onto Tetrakis-Thiomethyl-C-4-Methoxyphenylcalix[4]resorcinarene,” Indo. J. Chem., vol. 12, no. 1. pp. 49-56, 2012,

doi: 10.22146/ijc.21371.

[13] P. Santoso, C. Anwar, Jumina, D. Siswanta, Suharso, and Ohto, K., “Synthesis of a Novel Calix[4]resorcinarene-Chitosan Hybrid,” Orient. J. Chem., vol. 34, no. 1, pp. 30-37, 2018,

doi: 10.13005/ojc/340103.

[14] S. B. Utomo and Y. S. Anggun, “Sintesis C-4-karboksifenil-kaliks[4]resorsinarena dan Studi Adsorpsinya terhadap Ion Logam Ag(I),” Seminar Nasional Kimia dan Pendidikan Kimia XII (SN-KPK XII), P.Kimia PMIPA FKIP UNS, Surakarta 205-213, 2021.

Google Scholar

[15] S. B. Utomo, M. Fujiyanti, W. P. Lestari, and S. Mulyani, “Antibacterial Activity Test of the C-4-methoxyphenylcalix[4]resorcinarene Compound Modified by HexadecyltrimethylammoniumBromide against Staphylococcus aureus and Escherichia coli Bacteria,” Jurnal Kimia dan Pendidikan Kimia (JKPK), vol. 3, no. 3, pp. 201-209, 2018,

doi: 10.20961/jkpk.v3i3.22742.

[16] S. B. Utomo, A. Y. Solihah, and M. I. Fadilah, “The Exploration of C-4-methoxyphenyl-5,11,17,23-tetracarboxylcalix[4]resorcinarene as Antibacterial Agent,” Mor. J. Chem., vol. 10, no. 2, pp. 269-278, 2022,

doi: 10.48317/IMIST.PRSM/morjchem-v10i2.32641.

[17] X. Cao, X. Liu, J. Zhu, L. Wang, S. Liu, and G. Yang, “Characterization of phosphorus sorption on the sediments of Yangtze River Estuary and its adjacent areas,” Marine Pollution Bulletin, vol. 114, pp. 277-284, 2017,

doi: 10.1016/j.marpolbul.2016.09.026.

[18] M. Handayani & E Sulistiyono, “Uji Persamaan Langmuir dan Freundlich Pada Penyerapan Limbah Chrom (Vi) Oleh Zeolit,” Prosiding Seminar Nasional Sains dan Teknologi Nuklir PTNBR – BATAN Bandung, 2009.

Google Scholar

[19] P. Mulyono, & Wibisono, “Kinetika Adsorpsi Amoniak dalam Air dengan Karbon Aktif,” Media Teknik, No.2. pp. 36-42, ISSN: 0216-3012, 2007.

Google Scholar

[20] Suharso, Buhani, & Aprilia, L, “Pengaruh Senyawa Turunan Kaliksarena dalam Menghambat Pembentukan Kerak Kalsium Karbonat (CaCO3),” Prosiding Semirata FMIPA Unila, vol. 1, no. 1, pp 495–503, 2013.

Google Scholar

Refbacks

  • There are currently no refbacks.