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Kepok Banana Peels as Biosorbent for Mercury Sorption from Artificial Wastewater
Abstract
The present study used adsorbents from Kepok banana peel to remove Hg (II) from artificial wastewater. Kepok banana peels are the most abundant waste from several products bananas processed. One of the ways to reduce that waste is by using it as an adsorbent. This study utilizes the adsorbent from kepok banana peels to remove Hg (II) from artificial wastewater. This is because Hg(II) is a heavy metal that is harmful A previous study showed a high amount of Hg(II) in Kuantan River, one of the River in Riau Province. The effect of initial metal concentration, adsorbent mass, and contact time was investigated to evaluate the maximum removal percentage and adsorption capacity of Kepok banana peels. The adsorption parameters studied were initial Hg (II) concentration [6.84, 7.02,8.38, and 10.05 mg/L], adsorbent mass [10,20,30 and 40 g], and contact time variations (3,5,7 and 9 hours) where the operating conditions were 250 ml of Hg metal solution was added to each adsorbent. FTIR spectra of adsorbent showed hydroxyl, carboxylic, and amine groups in Kepok banana peels. The adsorption process found that the metal concentration variation under 6.84 mg/L initial Hg (II) concentration conditions gave the highest removal percentage of 99.7 % and the highest adsorption capacity of 0,0758 mg/g under the condition of 10.05 mg/L initial Hg (II) concentration. Then at adsorbent mass variation, the highest removal percentage was 94.8 % with 40 grams adsorbent mass, and the highest adsorption capacity was 0.1587 mg/g when using 10 grams adsorbent. The contact time variations gave the highest removal percentage, 95.2 %, and the highest adsorption capacity, 0.0542 mg/g, during contact for 5 hours. This study showed that Kepok banana peels had good potential for removing Hg (II) ions and could be used as a good adsorbent for removing the Hg (II) from wastewater. .
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[1] A. Bakırdere, S., Yaroğlu, T., Tırık, N., Demiröz, M., Fidan, A. K., Maruldalı, O., & Karaca, “Determination of As, Cd, and Pb in tap water and bottled water samples by using optimized GFAAS system with Pd-Mg and Ni as matrix modifiers,” J. Spectrosc., 2013
[2] I. S. Nuraini, “Analisis Logam Berat Dalam Air Minum Isi Ulang (Amiu) Dengan Menggunakan Spektrofotometri Serapan Atom (SSA) Analysis Of The Levels Of Heavy Metal In Refill Using Atomic Absorption Spectrophotometry (AAS),” Fis. Gravitasi, vol. 14, no. 37, 2015.
[3] Mirdat, Y. S. Patadungan, and Isrun, “Status Logam Berat Merkuri (Hg) dalam Tanah pada Kawasan Pengolahan Tambang Emas di Kelurahan Poboya, Kota Palu,” e-Journal Agrotekbis, vol. 1, no. 2, pp. 127–134, 2013.
[4] D. Arifiyana and V. A. Devianti, “Biosorption of Fe (II) Ions from Aqueous Solution Using Kepok Banana Peel (Musa Acuminate),” J. Kim. dan Pendidik. Kim., vol. 6, no. 2, pp. 206–215, 2021.
[5] B. T. Setiabudi, “Penyebaran Merkuri Akibat Usaha Pertambangan Emas di Daerah Sangon, Kabupaten Kulon Progo, D.I. Yogyakarta.,” 2005.
[6] M. Stancheva, L. Makedonski, and E. Petrova, “Determination of heavy metals (Pb, Cd, As and Hg) in Black Sea grey mullet (Mugil cephalus),” Bulg. J. Agric. Sci., vol. 19, no. SUPPL. 1, pp. 30–34, 2013.
[7] Badan Pusat Statistik Provinsi Riau, Statistik Air Bersih Provinsi Riau. Pekanbaru: CV.MN.Grafika, 2018.
[8] P. A. R. Yulis, “Analisis Kadar Logam Merkuri (Hg) dan (pH) Air Sungai Kuantan Terdampak Penambangan Emas Tanpa Izin (PETI),” Orbital J. Pendidik. Kim., vol. 2, no. 1, pp. 28–36, 2018.
[9] P. A. R. Yulis and Desti 2, “Penentuan Kadar Logam Berat Air Sungai Singingi Terdampak Penambangan Emas Tanpa Izin (Peti),” J. Katalisator, vol. 5, no. 2, pp. 188–196, 2020.
[10] P. A. R. Y. Yelfira Saria* and Abstract., “Reduction of Fe Levels in Groundwater Using Aeration - Filtration Method with,” J. Ilmu Kim. dan Terap., vol. 5, no. 113, pp. 110–115, 2021.
[11] F. M. Arief Yandra Putra, “Analisis Warna, Derajat Keasaman dan Kadar Logam Besi Air Tanah Kecamatan Kubu Babussalam, Rokan Hilir, Riau,” J. Katalisator, vol. 4, no. 1, pp. 9–14, 2019.
[12] Musafira; and Dzulkifli;, “Penyerapan Ion Logam Merkuri Menggunakan Arang Aktif Limbah Kulit Pisang Kepok (Musa paradisiaca Formatypica),” KOVALEN J. Ris. Kim., vol. 6, no. 1, pp. 39–44, 2020, doi: 10.22487/kovalen.2020.v6.i1.15043.
[13] E. Fabre, C. B. Lopes, C. Vale, E. Pereira, and C. M. Silva, “Valuation of banana peels as an effective biosorbent for mercury removal under low environmental concentrations,” Sci. Total Environ., vol. 709, p. 135883, 2020, doi: 10.1016/j.scitotenv.2019.135883.
[14] D. Yollanda, E. Nasra, D. K. I. Dewata, and U. K. Nizar, “Pengaruh Ion Cu2+, Zn2+, Cd2+ dan Cr3+ Terhadap Peyerapan Logam Pb2+ Menggunakan Kulit Pisang Kepok (Musa Paradisiaca L) …,” Menara Ilmu, vol. XIII, no. 2, pp. 171–177, 2019,
[15] Budiman;Hamidah;Hasria, “Limbah Kulit Pisang Kepok (Musa acuminate) Sebagai Biofilter Zat Besi (Fe) Dan Zat Kapur (CaCO3),” Promot. J. Kesehat. Masy., vol. 8, no. 2, pp. 152–158, 2018, doi: 10.31934/promotif.v8i2.497.
[16] L. K. D. N. S. Wardhani, “Uji Aktivitas Antibakteri Ekstrak Etil Asetat Daun Binahong (Anredera Scandens (L.) Moq.) Terhadap Shigella Flexneri Beserta Profil Kromatografi Lapis Tipis,” J. Ilm. Kefarmasian, vol. 2, no. 1, pp. 1-16., 2012.
[17] T. Zaidan, “Banana Peel as Removal Agent for Sulfide from Sulfur Springs Water,” vol. 3, no. 10, pp. 27–37, 2013.
[18] V. Viena, E. Elvitriana, and S. Wardani, “Application of banana peels waste as adsorbents for the removal of CO2, NO, NOx, and SO2 gases from motorcycle emissions,” IOP Conf. Ser. Mater. Sci. Eng., vol. 334, no. 1, 2018, doi: 10.1088/1757-899X/334/1/012037.
[19] N. B. Sumanik, E. Nurvitasari, R. Z. Maarebia, and J. Langkong, “Decrease of lead levels of leachate with banana skin adsorbent,” IOP Conf. Ser. Earth Environ. Sci., vol. 343, no. 1, 2019, doi: 10.1088/1755-1315/343/1/012172.
[20] H. Anom;, “Bioadsorben Kulit Pisang Kepok (Musa Acuminate L.) Dalam Menurunkan Kadar Timbal (Pb) Pada Larutan Pb,” J. Penelit. Kesehat. Suara Forikes, vol. 10, no. 4, pp. 1–7, 2019.
[21] M. I. Padam, B. S., Tin, H. S., Chye, F. Y., ; Abdullah, “). Banana by-products: an under-utilized renewable food biomass with great potential,” . J. food Sci. Technol., vol. 51, no. 12, pp. 3527-3545., 2014.
[22] A. A. Oladipo, E. O. Ahaka, and M. Gazi, “High adsorptive potential of calcined magnetic biochar derived from banana peels for Cu2+, Hg2+, and Zn2+ ions removal in single and ternary systems,” Environ. Sci. Pollut. Res., vol. 26, no. 31, pp. 31887–31899, 2019, doi: 10.1007/s11356-019-06321-5.
[23] W. Widjanarko;, “Kinetika Adsorpsi Zat Warna Congo Red Dan Rhodamine B Dengan Menggunakan Serabut Kelapa Dan Ampas Tebu,” J. Tek. Kim. Indones., vol. 5, no. 3, pp. 461–467, 2006.
[24] P. Nasir La Hasan ; Zakir, M; Budi, “Desilikasi karbon aktif sekam padi sebagai adsorben hg pada limbah pengolahan emas di kabupaten buru propinsi maluku,” Indones. Chim. Acta, vol. 7, no. 2, pp. 1–11, 2015,
[25] A. dan Imani and T. Sukwika, “Karbon Aktif Ampas Tebu sebagai Adsorben Penurun Kadar Besi dan Mangan Limbah Air Asam Tambang,” J. Teknol., vol. 13, no. 1, pp. 33–42, 2021, [Online]. Available: https://dx.doi.org/10.24853/jurtek.13.1.33-42.
[26] B. Rahadi, A. T. S. Haji, and I. Robbaniyah, “Analisis Penurunan Konsentrasi Methyl Orange Dengan Biosorben Kulit Pisang Cavendish (Musa Acuminata Cv. Cavendish),” J. Sumberd. Alam dan Lingkung., vol. 6, no. 2, pp. 29–35, 2019, doi: 10.21776/ub.jsal.2019.006.02.5.
[27] I. Satria, R. Putra, E. Z. Alharissa, and H. A. Rachma, “Penurunan Kadar Pb ( II ) Dan Mn ( II ) Pada Sungai Code Dengan Adsorben Limbah Kulit Pisang,” Semin. Nas. Tek. Kim. Ecosmart, no. Ii, pp. 78–89, 2018.
[28] D. Arifiyana and V. A. Devianti, “Biosorpsi Logam Besi (Fe) Dalam Media Limbah Cair Artifisial Menggunakan Adsorben kulit pisang kepok (Musa acuminate),” J. Kim. Ris., vol. 5, no. 1, pp. 1–8, 2020, doi: 10.20473/jkr.v5i1.20245.
[29] R. Rahmi and Sajidah, “Pemanfaatan Adsorben Alami (Biosorben) Untuk Mengurangi Kadar Timbal(Pb) dalam Limbah Cair,” Pros. Semin. Nas. Biot., pp. 271–279, 2017.
[30] S. Lestari, “Pengaruh berat dan waktu kontak untuk adsorpsi Timbal(II) oleh adsorben dari kulit batang jambu biji (Psidium guava L.),” J. Kim. Mulawarman, vol. 8, no. 1, pp. 7–10, 2010.
[31] I. D. Putri, S. Daud, and S. Elystia, “Pengaruh Massa Dan Waktu Kontak Adsorben Cangkang Buah Ketapang Terhadap Efisiensi Penyisihan Logam Fe Dan Zat Organik Pada Air Gambut,” Jom FTEKNIK, vol. 6, no. 2, pp. 1–13, 2019.
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