Synergy of Carbon Nanofiber Innovation from Zinc Oxide Modified Sugar Palm Fiber as Advanced Materials for Arsenic Heavy Metal Waste Remediation

Elisabeth Nugrahini, Lina Mahardiani, Ida Setiarini, Wieke Helma Anjelina

Abstract

Heavy metal wastes cause water pollution. One of them is very toxic arsenic heavy metal waste; thus, treating them before they are released freely into the waters is necessary. In this case, the manufacture of carbon nanofibers (CNF) from sugar palm fiber waste is an innovation that can produce adsorbents to remediate heavy metals, thereby increasing the use value of sugar palm fiber waste. Carbon nanofiber from palm fiber (Arenga pinnata) was modified with ZnO metal, with varying concentrations of 0.1%, 1%, and 10%, in 1 gram of carbon nanofiber. Carbon nanofibers were made by carbonizing sugar palm fibers at 300oC for two hours. Furthermore, wet impregnation was carried out with Zn(CH3COO)2.2H2O and ended with calcination at 250oC for an hour, resulting in black nanofiber powder. This research was conducted to determine the effect of ZnO concentration on the characteristics of the carbon nanofiber produced and its effectiveness in remediating heavy metal arsenic. The ZnO/carbon nanofiber adsorbent material was then characterized using FTIR, XRD, and SEM analyses. Determination of the absorption of ZnO/carbon nanofibers on heavy metal arsenic was also assessed employing AAS analysis.

Keywords

Sugar palm fiber, Carbon nanofibers;ZnO;Heavy metal adsorption; and arsenic

Full Text:

PDF

References

[1] A. Masyruroh and E. Karyadi, “Analisa Terhadap Kualitas Air Permukaan Rumah Sakit Umum Daerah Kabupaten Serang”, Fondasi: Jurnal Teknik Sipil, vol. 2, no 2, pp. 99–110, 2013

DOI: 10.36055/jft.v2i2.1724.

[2] N. V. Sari, “Proses Pembuatan Keris di Padepokan Keris Brojobuwono Desa Wonosari Kecamatan Gondangrejo Kabupaten Karanganyar”, Skripsi UNS, pp. 5–45, 2014

Google Scholar

[3] R. Adhani and Husaini, “Logam Berat Sekitar Manusia”, Banjarmasin: Lambung Mangkurat University Press, 132-134, 2017.

ISBN: 978-602-6483-47-8.

[4] J. C. Mabuat, S. S. Maddusa, and H. Boky, “Analisis Kandungan Logam Berat Arsen (As) Pada Air, Ikan, Kerang, dan Sedimen di Daerah Aliran Sungai Tondano Tahun 2017” Jurnal Kesehatan Masyarakat Universitas Sam Ratulangi, vol. 6, no. 3, pp. 1–11, 2017

Google Scholar

[5] A. R. Faradilla, H. Yulinawati, and E. Suswantoro, “Pemanfaatan Flyash Sebagai Adsorben Karbon Monoksida dan Karbon Dioksida pada Emisi Kendaraan Bermotor”, Seminar Nasional Cendekiawan, pp. 1–8, 2016.

ISSN (E): 2540-7589

[6] T. Mazoochi, M. Hamadanian, M. Ahmadi, and V. Jabbari, “Investigation on the Morphological Characteristics of Nanofiberous Membrane as Electrospun in the Different Processing Parameters”, International Journal of Industrial Chemistry, vol. 3, no. 2, pp. 1–8.

DOI: 10.1186/2228-5547-3-2.

[7] D. Sudarsono, “Pemanfaatan Limbah Serat Aren Sebagai Bahan Baku Pembuatan Material Komposit/Papan Partikel”, Prosiding Seminar Nasional Metalurgi Material (SENAMM), 2013.

[8] M. R. Ishak, S. M. Sapuan, Z. Leman, and M. Z. A. Rahman, “Sugar palm (Arenga pinnata): Its fibres, polymers and composites”, Carbohydrate Polymers, vol. 91, no. 2, pp. 699–710, 2013.

DOI: 10.1016/j.carbpol.2012.07.073.

[9] K. S. Babu, A. R. Reddy, Ch. Sujatha, and K. V. Reddy, “Effects of Precursor, Temperature, Surface Area and Excitation Wavelength on Photoluminescence of ZnO/Mesoporous Silica Nanocomposite”, Ceramics International, vol. 39, no. 3, pp. 3055–3064, 2013.

DOI: 10.1016/j.ceramint.2012.09.085.

[10] H. Wen, X. Zhou, Z. Shen, Z. Peng, H. Chen, L. Hao, and H. Zhou, “Synthesis of ZnO nanoparticles supported on mesoporous SBA-15 with coordination effect -assist for anti-bacterial assessment”, Colloids and Surfaces B: Biointerfaces, vol. 181, pp. 285-295, 2019.

DOI: 10.1016/j.colsurfb.2019.05.055.

[11] U. Septiani, I. Ella, and Syukri, “Pembuatan dan Karakterisasi Katalis Zno/Karbon Aktif Dengan Metode Solid State dan Uji Aktifitas Katalitiknya pada Degradasi Rhodamin B. Jurnal Riset Kimia, vol. 7, no. 2, pp. 180, 2014.

DOI: 10.25077/jrk.v7i2.186.

[12] Rismang, H. S. Syamsidar, K. Ramadani, “Sintesis Zeolit dari Abu Layang dengan Metode Hidrotermal dan Uji Adsorptivitas terhadap logam Timbal (Pb)”, Al-Kimia, vol. 5, no. 2, pp. 127-135, 2017

DOI: 10.24252/al-kimia.v5i2.3394.

[13] J. Chandra, N. George, and S. K. Naratanankutty, “Isolation and Characterization of Cellulose Nanofibrils From Arecanut Husk Fibre”, Jounal carbohydrate Polymers, vol. 142, pp. 158-166, 2016.

DOI: 10.1016/j.carbpol.2016.01.015.

[14] Maryono, Sudding and Rahmawati, “Pembuatan dan Analisis Mutu Briket Arang Tempurung Kelapa ditinjau dari Kadar Kanji”, Jurnal Chemica, vol. 14, no. 1, pp. 74–83, 2013

DOI: 10.35580/chemica.v14i1.795.

[15] H. Kumar, and R. Rani, “Structural and Optical Characterization of ZnO Nanoparticles Synthesized by Microemulsion Route”, International Letters of Chemistry, Physics and Astronomy, vol. 19, pp. 26-36, 2013

DOI: 10.18052/www.scipress.com/ILCPA.19.26.

[16] H. Sanjaya, “Degradasi Metil Violet Menggunakan Katalis Zno-Tio2 Secara Fotosonolisis”, Eksakta: Berkala Ilmiah Bidang Mipa, vol. 19, no. 1, pp. 91–99, 2018.

DOI: 10.24036/eksakta/vol19-iss1/131.

[17] Z. N. Kayani, M. Iqbal, S. Riaz, R. Zia, and S. Naseem, “Fabrication and Properties of Zinc Oxide Thin Film Prepared by Sol-Gel Dip Coating Method. Journal Material Science-Poland, vol. 33, no. 3, pp. 515-520, 2015.

DOI: 10.1515/msp-2015-0085.

[18] R. A. Ilyas, S. M. Sapuan, R. Ibrahim, H. Abral, M. R. Ishak, E. S. Zainudin, M. Asrofi, M. S. N. Atikah, M. R. M. Huzaifah, A. M. Radzi, A. M. N. Azammi, M. A. Shaharuzaman, N. M. Nurrazi, E. Syafri, N. H. Sari, M. N. F. Noorahim, R. Jumaidin, “Sugar palm (Arenga Pinnata [Wurmb.] Merr) Cellulosic Fibre Hierarchy : AComprehensive Approach from Macro to Nano Scale”, Journal of Materials Research and Technology, vol. 8, no. 3, pp. 2753–2766, 2019.

DOI: 10.1016/j.jmrt.2019.04.011.

[19] S. Alfarisa, P. L. Toruan, Atina, W. S. B. Dwandaru, and R. N. Safitri, “Morphological and Structural Studies of Zno Micro-Nanorod Structures Synthesized Using a Low-Cost Hydrothermal Method”, Makara journal of Science, vol. 22, no. 2, pp. 59-66, 2018.

DOI: 10.7454/mss.v22i2.8243.

[20] H. A. Sani, M. B. Ahmad, and T. A. Saleh, “Synthesis of Zinc Oxide/Talc Nanocomposite for Enhanced Lead Adsorption from Aqueous Solutions”, Royal Society of Chemistry, vol. 110, no. 6, pp. 108819-108827, 2016.

DOI: 10.1039/C6RA24615J.

[21] P. Ingale, K. Knemeyer, M. P. Hermida, R. N. d’Alnoncourt, A. Thomas, and F. Rosowski, “Atomic Layer Deposition of ZnO on Mesoporous Silica: Insights into Growth Behavior of ZnO via In-Situ Thermogravimetric Analysis”, Nanomaterials, vol. 10, no. 5, pp. 981, 2020.

DOI: 10.3390/nano10050981.

[22] P. Bindu, and S. Thomas, “Estimation of lattice strain in ZnO nanoparticles: X-ray peak profile analysis”, J Theor Appl Phys, vol. 8, pp. 123-134, 2014.

DOI: 10.1007/s40094-014-0141-9.

[23] C. Jing, X. Wen, X. Shi, and R. Pan, “Synthesis of Zinc Oxide/Activated Carbon Nano-Composites and Photodegradation of Rhodamin B”, Journal Environmental Engineering Science, vol. 2, no. 6, pp. 393-399, 2012.

DOI: 10.1089/ees.2010.0260.

[24] R. Slamet, Arbianti and Daryanto, "Pengolahan Limbah Organik (Fenol) dan Logam Berat (Cr6+) atau (Pt4+) secara Stimulan dengan Fotokatalis TiO2, ZnO-TiO2, dan CdS-TiO2", Makara Journal of Technology, vol. 9, no. 2, pp. 66-71, 2005.

DOI: 10.7454/mst.v9i2.363.

[25] T.H. Pujianto, “Pengaruh Konsentrasi Natrium Hidroksida dan Temperatur 22 Anil terhadap Struktur Nano dan Tingkat Kristalinitas TiO2 Nanotubes”, Prosiding Seminar Material Metalurgi, LIPI, Serpong, 2009.

Google Scholar

DOI: https://doi.org/10.20961/jkpk.v7i2.55969

Refbacks

  • There are currently no refbacks.


Bookmark and Share