Effect of Plasticizer Addition on The Characteristics of Chitosan-Alginate Edible Film

Atmanto Heru Wibowo, Helmi Fehragucci, Candra Purnawan

Abstract

The edible film of chitosan-alginate in this study showed characteristics of the physical and mechanical properties when various plasticizers of polyethylene glycol/PEG, polyvinyl alcohol/PVA, and glycerol were added into the origin film. It was also found that chitosan content in the edible film contributed to the change in the physical properties and the conductivity of the film. The general effect on the film because of the addition of plasticizers was the decrease of the tensile strength, the increase of the films' elongation, and the increase of the water vapor permeability (WVP). Among other plasticizers, PEG attracted the most attention in which it affected the most significant change on the properties. Meanwhile, the higher chitosan content in the chitosan-alginate film affected the increase of the tensile strength and the decrease of the elongation value, and the decrease of the WVP on the film. Characterization using FT-IR spectrophotometer showed that no chemical interaction was formed due to the mixing of alginate-chitosan in the film. Instead, only the physical blending of chitosan-alginate was formed in the edible film.

Keywords

alginate; chitosan; glycerol; PEG; PVA.

Full Text:

PDF

References

Bouyer, D., Méricq, J.-P., Wlodarczyk, D., Soussan, L., and Faur, C., 2023. How Mass and Heat Transfers Could Affect Chitosan Membrane Formation Via an Enzymatic Gelation. Journal of Membrane Science, 669 (121298), 1–13. https://doi.org/10.1016/j.memsci.2022.121298.

Castro-Muñoz, R., Cichocki, Ł., Plata-Gryl, M., Boczkaj, G., and Galiano, F., 2023. Performance Tuning of Chitosan-Based Membranes by Protonated 2-Pyrrolidone-5-Carboxylic Acid-Sulfolane DES for Effective Water/Ethanol Separation by Pervaporation. Chemical Engineering Research and Design, 19(1), 401–413. https://doi.org/10.1016/j.cherd.2023.01.049.

Chen, S., Gao, J., Luo, X., Sun, Y., Jin, W., and He, R., 2023. Therapy of Reprogrammable Immune Activating Supramolecular-Based Chitosan Membranes for Skin Regeneration. Materials and Design, 227(111713), 1–8. https://doi.org/10.1016/j.matdes.2023.111713.

Chen, Z., Li, P., Ji, Q., Xing, Y., Ma, X., and Xia, Y., 2023. All-Polysaccharide Composite Films Based on Calcium Alginate Reinforced Synergistically by Multidimensional Cellulose and Hemicellulose Fractionated from Corn Husks. Materials Today Communications, 34(105090), 1–10. https://doi.org/10.1016/j.mtcomm.2022.105090.

Choi, I., Lee, Y., Lyu, J.S., Lee, J.-S., and Han, J., 2022. Characterization of Ionically Crosslinked Alginate Films: Effect of Different Anion-Based Metal Cations on The Improvement of Water-Resistant Properties. Food Hydrocolloids, 131(107785), 1–9. https://doi.org/10.1016/j.foodhyd.2022.107785.

Das, B., Gaur, S.S., Katha, A.R., Wang, C.T., and Katiyar, V., 2023. Hair Hydrolysate Functionalized Cellulose Nanocrystal Based Chitosan Membrane to Harness Power from Wastewater Fed Mfcs. International Journal of Hydrogen Energy, 48, 9451–9461. https://doi.org/10.1016/j.ijhydene.2022.12.054.

Donhowe, G. and Fennema, O., 1993. Water Vapour and Oxygen Permeability of Wax Film. Journal Amateur Oil Science, 70(9), 867–873. https://doi.org/10.1007/BF02545345.

Hui, Y. H., 2006. Handbook of Food Science, Technology, and, Engineering Volume I. CRC Press, USA.

Karimi-Khorrami, N., Radi, M., Amiri, S., Abedi, E., and McClements, D.J., 2022. Fabrication, Characterization, and Performance of Antimicrobial Alginate-Based Films Containing Thymol-Loaded Lipid Nanoparticles: Comparison of Nanoemulsions and Nanostructured Lipid Carriers. International Journal of Biological Macromolecules, 207, 801–812. https://doi.org/10.1016/j.ijbiomac.2022.03.149.

Kong, Y., Zhang, W., He, T., Yang, X., Bi, W., Li, J., Yang, W., and Chen, W., 2023. Asymmetric Wettable Polycaprolactone-Chitosan/Chitosan Oligosaccharide Nanofibrous Membrane as Antibacterial Dressings. Carbohydrate Polymers, 304(120485), 1–10. https://doi.org/10.1016/j.carbpol.2022.120485.

Lieberman, E. R. and Gilbert, S. D., 1973. Gas Permeation of Collagen Films as Affected bt Cross Linkage Moitsure and Plasticizer Content. Jounal Of Polymer Science, 41, 33–43. https://doi.org/10.1002/polc.5070410106.

Rodrigues, F.J., Cedran, M.F., Bicas, J.L., and Sato, H.H., 2023. Inhibitory Effect of Reuterin-Producing Limosilactobacillus Reuteri and Edible Alginate-Konjac Gum Film Against Foodborne Pathogens and Spoilage Microorganisms. Food Bioscience, 52 (102443), 1–9. https://doi.org/10.1016/j.fbio.2023.102443.

Santos, L.G., Alves-Silva, G.F., and Martins, V.G., 2022. Active-Intelligent and Biodegradable Sodium Alginate Films Loaded with Clitoria Ternatea Anthocyanin-Rich Extract to Preserve and Monitor Food Freshness. International Journal of Biological Macromolecules, 220, 866–877. https://doi.org/10.1016/j.ijbiomac.2022.08.120.

Schöbel, L., Karakaya, E., Detsch, R., and Boccaccini, A.R., 2023. Preparation of Compact Alginate Films for 2D in Vitro Studies: Challenges and Strategies for Improvement. Materials Letters, 134103. https://doi.org/10.1016/j.matlet.2023.134103.

Soontarapa, K., Ampairojanawong, R., and Palakul, T., 2023. Esterification and Transesterification of Palm Fatty Acid Distillate in Chitosan Membrane Reactor. Fuel, 339 (126918). https://doi.org/10.1016/j.fuel.2022.126918.

Zakaria, S.A., Ahmadi, S.H., and Amini, M.H., 2023. Alginate/Dye Composite Film-Based Colorimetric Sensor For Ammonia Sensing: Chicken Spoilage. Food Control, 147(109575). https://doi.org/10.1016/j.foodcont.2022.109575.

Zhang, M. and Chen, H., 2023. Development and Characterization of Starch‑Sodium Alginate-Montmorillonite Biodegradable Antibacterial Films. International Journal of Biological Macromolecules, 233(123462).

Zhong, Y., Yang, M., M., Chen, J., Mi, H., Ge, Y., Lv, J., and Li, J., 2023. Pre-Crosslinking with Putrescine Improves Mechanical and Thermal Properties of Alginate Film. Journal of Food Engineering, 340(111314).

Refbacks

  • There are currently no refbacks.