Analisys of Tensile Strength, Wear Rate, and Cristallinity of Biocomposite Nano-HA/Magnesium/Shellac Reinforced Cantula Fiber for Bone Screw Material

Dea Pawestry Utami, Joko Triyono, Wijang Wisnu Raharjo, Rachmad Imbang Tritjahjono

Abstract

Accidents are a major cause of fractures in Indonesia. One of the treatments for fractures is bone screws with support plates that are placed on broken bone. Currently, many biomaterials for bone screws are being developed which have biodegradable properties so that post-operative bone healing is not required. The purpose of this study was to determine the effect of cantula fiber addition on tensile strength, wear rate, and crystallinity of nano-HA/magnesium/shellac bio-composite for bone screw materials. Nano-HA/magnesium/shellac/cantula fiber materials were mixed using a blender. The material was mixed with a magnesium/hydroxyapatite ratio of 70/30 and cantula fiber was added with variations of 0%, 10%, 20% and 30% of total volume. After that, material mixture was compacted with a pressure of 300 MPa for 10 minutes. Then sintering process was carried out at temperature of 140 °C for two hours. The results showed that the highest tensile strength value was 7.86 MPa at 30% variation. The lowest wear rate was 0.31 x 10-3 mm3/Nm at 30% variation. The highest crystallinity in X-Ray Diffraction observations was obtained at 30% variation, which was 79.65%.

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References

1. L. Liu, K. Gebresellasie, B. Collins, H. Zhang, Z. Xu, J. Sankar, Y. C. Lee, and Y. Yun, “Degradation rates of pure zinc, magnesium, and magnesium alloys measured by volume loss, mass loss, and hydrogen evolution,” Appl. Sci., vol 8, no. 9, article no. 1459, 2018.

2. M. Rahman, Y. Li, and C. Wen, “HA Coating on Mg Alloys for Biomedical Applications: A Review,” J. Magnes. Alloy., vol. 8, no. 3, pp. 929-943, 2020.

3. M. Mozartha, “Hydroxyapatite and its Applications in Dentistry,” Riskesdas 2018, vol. 3, no. 2, 2015. (in Indonesian).

4. J. Triyono, R. Adityawan, P. Dananjaya, D. F. Smaradhana, and A. Masykur, “Characterization and Biodegradation Rate of Hydroxyapatite/Shellac/Sorghum for Bone Scaffold Materials,” Cogent Eng., vol. 8, no. 1, article no. 1884335, 2021.

5. W. W. Raharjo, R. Soenoko, Y. S. Irawan, and A. Suprapto, “The Influence of Chemical Treatments on Cantala Fiber Properties and Interfacial Bonding of Cantala Fiber/Recycled High Density Polyethylene (rHDPE),” J. Nat. Fibers, vol. 15, no. 1, pp. 98-111, 2018.

6. L. Røhl, E. Larsen, F. Linde, A. Odgaard, and J. Jørgensen, “Tensile and compressive properties of cancellous bone,” J. Biomech., vol. 24, no. 12, pp. 11431149, 1991.

7. C. Prakash, H. K. Kansal, B. S. Pabla, S. Puri, and A. Aggarwal, “Electric discharge machining - A potential choice for surface modification of metallic implants for orthopedic applications: A review,” Proc. Inst. Mech. Eng. Part B J. Eng. Manuf., vol. 230, no. 2, pp. 331353, 2016.

8. E. Mahmuda, S. Savetlana, and Sugiyanto, “Effect of Fiber Length on Tensile Strength,” J. Ilm. Tek. Mesin, vol. 1, pp. 7984, 2013. (in Indonesian).

9. A. Fathoni, W. W. Raharjo, and T. Triyono, “Pengaruh perlakuan panas serat terhadap sifat tarik serat tunggal dan komposit cantula-rHDPE,” Simetris: Jurnal Teknik Mesin, Elektro dan Ilmu Komputer, vol. 8, no. 1, pp. 67-74, 2017. (in Indonesian).

10. W. W. Rahardjo, E. Pujiyanto, B. A. Saputro, A. Majid, and J. Triyono, “Agave Cantula fiber-reinforced bio-composites of hydroxyapatite/shellac as a dental material,” J. Nat. Fibers, vol. 19, no. 16, pp. 13012-13024, 2022.

11. M. Jawaiid, R. Nagarajan, J. Sukumaran, and P. De Baets, Synthesis and Tribological Applications of Hybrid Material, New Jersey: John Wiley & Sons, 2018.

12. L. Septiani, Yudyanto, and Hartatiek, The Effect of Maturation Time on the Degree of Crystallinity and Hardness of Nano-Hydroxyapatite from Calcite Druju Malang, Malang: Universitas Negeri Malang, 2009. (in Indonesian).

13. Sunardi, M. Fawaid, and M. F. R. Noor, “Variasi Campuran Fly Ash Batubara untuk Material Komposit,” Jurnal Teknik Mesin Untirta, vol. I, no. 1, pp. 90-102, 2015. (in Indonesian).

14. Suryadi, Sintesis dan karakterisasi Biomaterial Hidroksiapatit dengan proses pengendapan kimia basah, Depok: Universitas Indonesia, 2011. (in Indonesia).

15. J. Wang, L. Chen, and Y. He, “Preparation of environmental friendly coatings based on natural shellac modified by diamine and its applications for copper protection,” Prog. Org. Coatings, vol. 62, no. 3, pp. 307312, 2008.

16. Ridwan, T. Rihayat, A. Ilmi, and N. Aidy, “Pengaruh sifat material dan termal komposit pla (poly lactid acid)/coconut fiber (sabut kelapa) dengan modifiksi perendaman naoh,” Jurnal Sains dan Teknologi Reaksi, vol. 20, no. 2, pp. 19, 2022. (in Indonesian).

17. N. A. Arini, M. Bara, D. Wahyuni, and A. Bahan, “Analysis of the Effect of Hydrolysis Time on the Mechanical Properties of Crystalline Cellulose from a Mixture of Belian, Bengkirai, Teak and Meranti Wood Sawdust,” Positron, vol. 5, no. 2, pp. 7073, 2015. (in Indonesian).

18. M. Sumiati, D. Wahyuni, and M. B. Malino, “Analisis Hubungan Konsentrasi Asam saat Hidrolisis, Derajat Kristalinitas dan Sifat Mekanis Selulosa Kristalin dari Serbuk Gergaji Kayu,” Prisma Fisika, vol. 4, no. 2, pp. 6468, 2016. (in Indonesian).

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