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The effect of molasses addition as a binder in the manufacturing of cow dung bio-pellets on their characteristics and combustion kinetics have been studied. The bio-pellets characterization included the physical and mechanical properties as well as the proximate analysis and calorific values. Thermogravimetric analysis (TGA) was carried out using a macro-TGA apparatus under a non-isothermal conditions and an oxidative atmosphere to study the thermal decomposition characteristics. Then, the first order Coast and Redfern method was used to determined the kinetic parameters of bio-pellets combustion. It was found that the ash content of bio-pellets were tended to decreased, while the volatile matter and fixed carbon were tended to increase with the addition of molasses. Nevertheless, the density, the axial compressive strength and the calorific values of bindered bio-pellets were decreased due to the higher amounts of water in the raw mixtures. Thermogravimetric analysis provided an information that the combustions of cow dung bio-pellets took place in three stages of decompositions The bindered bio-pellet began to decompose at lower temperatures than the binderless bio-pellet with a higher weight loss percentage. According to the comprehensive combustion characteristic index (S), the combustion performance of both binderless and bindered bio-pellets were similar. The addition of molasses as a binder tended to reduce the ignition temperature and activation energy for all stages of bio-pellets combustion.
Keywords:
Bio-pellet, Characterization, Cow Dung, Combustion Kinetics, Molasses
[1] Direktorat Statistik Peternakan, Perikanan, dan Kehutanan, “Peternakan Dalam Angka 2022”, Badan Pusat Statistik, Indonesia. ISSN: 2714-8416.
[2] M.A.K. Budiyanto, “Tipologi Pendayagunaan Kotoran Sapi dalam Upaya Mendukung Pertanian Organik di Desa Sumbersari Kecamatan Poncokusumo Kabupaten Malang”, GAMMA, vol. 7, no. 1, pp. 42-49, Sept., (2011). http://ejournal.umm.ac.id/index.php/gamma/article/view/1420.
[3] W. Wijayanti and M.N. Sasongko, “Reduksi Volume dan Pengarangan Kotoran Sapi dengan Metode Pirolisis”, Jurnal Rekayasa Mesin, vol. 3, no. 3, pp. 404-410, (2012). ISSN: 0216-468X
[4] A. Szymajda, G. Laska, M. Joka, “Assessment of Cow Dung Pellets as a Renewable Solid Fuel in Direct Combustion Technologies”, Energies, vol. 14, 1192, (2021). doi: https://doi.org/10.3390/en14041192
[5] L. Kaur, J. Singh, G. Gayathri, B. Negi, “Thermogravimetric Characterization of Cattle Manure as Pyrolysis and Combustion Feedstocks”, Int.J.Curr.Microbiol.App.Sci., Special Issue-11, pp. 2228-2237, (2020). ISSN: 2319-7706. http://www.ijcmas.com
[6] G. Zhu, J. Huang, Z. Wan, H. Ling, Q. Xu, "Cow Dung Gasification Process for Hydrogen Production Using Water Vapor as Gasification Agent”, Processes, vol. 10, 1257, (2022). doi: https://doi.org/10.3390/ pr10071257
[7] Badan Pusat Statistik Provinsi Jawa Tengah (Statistics of Jawa Tengah Province), “Populasi Ternak Menurut Kabupaten/Kota dan Jenis Ternak di Provinsi Jawa Tengah 2020-2022”, https://jateng.bps.go.id/indicator/ 24/75/1/populasi-ternak-menurut-kabupaten-kota-dan-jenis-ternak-diprovinsi-jawa-tengah-ekor-.html. Accessed on January 19, 2024.
[8] Wahyudi, “Penelitian Nilai Kalor Biomassa: Perbandingan Antara Hasil Pengujian dengan Hasil Perhitungan”, Jurnal Ilmiah Semesta Teknika, vol. 9, no. 2, pp. 208-220, (2006).
[9] G. Chen, S. He, Z. Cheng, Y. Guan, B. Yan, W. Ma, D.Y.C. Leung, “Comparison of kinetic analysis methods in thermal decomposition of cattle manure by themogravimetric analysis”, Bioresources Technology, vol. 243, pp. 69-77, (2017). doi: http://dx.doi.org/10.1016/j.biortech.2017.06.007
[10] Z. Akyurek, “Sustainable Valorization of Animal Manure and Recycled Polyester: Co-pyrolysis Synergy”, Sustainability, vol. 11, 2280, (2019). doi:10.3390/su11082280
[11] J.S. Tumuluru, C.T. Wright, J.R. Hess, K.L. Kenney, “A review of biomass densification systems to develop uniform feedstock commodities for bioenergy application”, Biofuels, Bioproducts and Biorefining, vol. 5, pp. 683-707, (2011). doi: 10.1002/bbb.324
[12] J. Jamradloedluk and C.Lertsatitthanakorn, “Influences of Mixing Ratios and Binder Types on Properties of Biomass Pellets”, Energy Procedia, vol. 138, pp. 1147-1152, (2017). doi: 10.1016/j.egypro.2017.10.223
[13] I.M.R. Badran, I.L. Ocampo, J.F.G. Trejo, J.S. Cruz, C.G. Antonio, “Production and characterization of fuel pellets from rice husk and wheat straw”, Renewable Energy, vol. 145, pp. 500-507, (2020). doi: 10.1016/j.renene.2019.06.048
[14] M. Iftikhar, A. Asghar, N. Ramzan, B. Sajjadi, W. Chen, “Biomass densification: Effect of cow dung on the physicochemical properties of wheat straw and rice husk based biomass pellets”, Biomass and Bioenergy, vol. 122, pp. 1-16, (2019). doi: https://doi.org/10.1016/j.biombioe.2019.01.005
[15] G. Jia, “Combustion Characteristics and Kinetic Analysis of Biomass Pellet Fuel Using Thermogravimetric Analysis”, Processes, vol. 10, 868, (2021). doi: https://doi.org/10.3390/pr9050868
[16] M. Ashraf, N. Ramzan, R.U. Khan, A.K. Durrani, “Analysis of mixed cattle manure: Kinetics and thermodynamic comparison of pyrolysis and combustion processes”, Case Studies in Thermal Engineering, vol. 26, 101078, (2021). doi: https://doi.org/10.1016/j.csite.2021.101078