Density Evaluation of Alkyl Ester from Different Types of Alcohol and Vegetable Oil

Dyah Retno Sawitri, Khusnul Azzam, Ani Chalwa Isnani, Darryl Al Husein

Abstract

ABSTRACT. Alkyl ester, also known as biodiesel, is an alternative renewable energy source and is produced through the reaction of vegetable oil and alcohol. One of the important characteristics of biodiesel lies in the density value. This study evaluates the density value of alkyl esters from several raw materials. The raw materials used include palm oil and rice bran oil. In comparison, the types of alcohol used include methanol, ethanol, and isopropanol. The density values of palm oil ethyl ester and rice bran oil ethyl ester were measured at 30 – 100°C. The density measurement results were then compared with the simulation results using ASPEN Plus® software. The density of alkyl esters was measured over a temperature range of 30-100°C. The density measurements were then compared with the simulation results using ASPEN Plus® software. The measurement and simulation results showed that the density was higher in the order ethyl > methyl > isopropyl ester for palm oil. When viewed from the vegetable oil, the density of rice bran oil ethyl ester is higher than that of palm oil ethyl ester. The results of measuring biodiesel from rice bran oil and palm oil at 40°C show that only the isopropyl ester has a density that does not meet the quality requirements of biodiesel as defined by the Indonesian National Standard. 

Keywords:

Biodiesel, Density, Palm oil, Rice bran oil 

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References

[1] Badan Pusat Statistik. Indonesia, Statistik Tanaman Perkebunan Tahunan Indonesia, 2025.

[2] Badan Pusat Statistik. Indonesia, Luas Panen dan Produksi Padi di Indonesia, 2025.

[3] N.A. Mohidem, N. Hashim, R. Shamsudin, H.C. Man, “Rice for Food Security : Revisiting Its Production, Diversity, Rice Milling Process and Nutrient Content,” (2022).

[4] A. Jumari, A.S. Rahmani, F.R. Riana, “Fraksinasi Kompleksasi Urea Pada Minyak Dedak Padi,” Ekuilibrium. 14 17–22 (2015).

[5] P. Maheshwari, M.B. Haider, M. Yusuf, J.J. Klemeš, A. Bokhari, M. Beg, A. Al-Othman, R. Kumar, A.K. Jaiswal, “A review on latest trends in cleaner biodiesel production: Role of feedstock, production methods, and catalysts,” J. Clean. Prod. 355 (2022). https://doi.org/10.1016/j.jclepro.2022.131588.

[6] I.A. Musa, “The effects of alcohol to oil molar ratios and the type of alcohol on biodiesel production using transesterification process,” Egypt. J. Pet. 25 21–31 (2016). https://doi.org/10.1016/j.ejpe.2015.06.007.

[7] M. Gotovuša, I. Pucko, M. Racar, F. Faraguna, “Biodiesel Produced from Propanol and Longer Chain Alcohols—Synthesis and Properties,” Energies. 15 (2022). https://doi.org/10.3390/en15144996.

[8] P. McCarthy, M.G. Rasul, S. Moazzem, “Comparison of the performance and emissions of different biodiesel blends against petroleum diesel,” Int. J. Low-Carbon Technol. 6 255–260 (2011). https://doi.org/10.1093/ijlct/ctr012.

[9] M. Canakci, H. Sanli, “Biodiesel production from various feedstocks and their effects on the fuel properties,” J. Ind. Microbiol. Biotechnol. 35 431–441 (2008). https://doi.org/10.1007/s10295-008-0337-6.

[10] S. Gahlyan, S. Maken, S.J. Park, “Measurement and modelling of solid-liquid equilibria, density and viscosity of fatty acid methyl or ethyl esters,” J. Mol. Liq. 314 113628 (2020). https://doi.org/10.1016/j.molliq.2020.113628.

[11] G. Tüccar, E. Tosun, E. Uludamar, “Investigations of Effects of Density and Viscosity of Diesel and Biodiesel Fuels on NOx and other Emission Formations,” Acad. Platf. J. Eng. Sci. 6 81–85 (2018). https://doi.org/10.21541/apjes.371015.

[12] M.A. Mujtaba, M.A. Kalam, H.H. Masjuki, L. Razzaq, H.M. Khan, M.E.M. Soudagar, M. Gul, W. Ahmed, V.D. Raju, R. Kumar, H.C. Ong, “Development of empirical correlations for density and viscosity estimation of ternary biodiesel blends,” Renew. Energy. 179 1447–1457 (2021). https://doi.org/10.1016/j.renene.2021.07.121.

[13] “SNI 7182:2015, Standar Nasional Indonesia - Biodiesel,” (n.d.).

[14] A.G.M. Ferreira, N.M. Carmen Talvera-Prieto, A.A. Portugal, R.J. Moreira, “REVIEW: Models for predicting viscosities of biodiesel fuels over extended ranges of temperature and pressure,” Fuel. 287 (2021). https://doi.org/10.1016/j.fuel.2020.119544.

[15] B. Sajjadi, A.A.A. Raman, H. Arandiyan, “A comprehensive review on properties of edible and non-edible vegetable oil-based biodiesel: Composition, specifications and prediction models,” Renew. Sustain. Energy Rev. 63 62–92 (2016). https://doi.org/10.1016/j.rser.2016.05.035.

[16] H. Rahman, J.P. Sitompul, S. Tjokrodiningrat, “The composition of fatty acids in several vegetable oils from Indonesia,” Biodiversitas. 23 2167–2176 (2022). https://doi.org/10.13057/biodiv/d230452.

[17] M.J. Pratas, S. Freitas, M.B. Oliveira, S.C. Monteiro, A.S. Lima, J.A.P. Coutinho, “Densities and viscosities of fatty acid methyl and ethyl esters,” J. Chem. Eng. Data. 55 3983–3990 (2010). https://doi.org/10.1021/je100042c.

[18] L.F. Ramírez Verduzco, “Density and viscosity of biodiesel as a function of temperature: Empirical models,” Renew. Sustain. Energy Rev. 19 652–665 (2013). https://doi.org/10.1016/j.rser.2012.11.022.

[19] S.K. Hoekman, A. Broch, C. Robbins, E. Ceniceros, M. Natarajan, “Review of biodiesel composition, properties, and specifications,” Renew. Sustain. Energy Rev. 16 143–169 (2012). https://doi.org/10.1016/j.rser.2011.07.143.

[20] A.T. Doppalapudi, A.K. Azad, M.M.K. Khan, A.M.T. Oo, “Optimization and simulation of Tucuma and Ungurahui biodiesel process parameters and their effects on fuel properties,” Energy Convers. Manag. X. 24 (2024). https://doi.org/10.1016/j.ecmx.2024.100721.

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