Effect of The Composition of TiO2 Additives on The Physical and Magnetic Properties Crystal Structure and Microstructure of BaFe12O19 Magnetic Ceramics

Ramlan Ramlan, Endah Puspita

Abstract

In this research, the manufacture of barium hexaferrite (BaFe12O19) magnetic ceramics and the addition of titanium dioxide (TiO2) additives with variations of 0%: 0.3%: 0.6% and 0.9% used the powder metallurgical method. The characterization used in this study is the measurement of density, porosity, X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), Vibrating Sample Magnetometer (VSM), and Impulse Magnetizer K-Series. Based on the results of density and porosity measurements, the highest values were 4.95 g/cm3 and 5.45%, respectively. XRD results showed the formation of a BaFe12O19 phase with some impurities at 0% (Fe2O3), 0.3% and 0.9% (Ti6O11), and 0.6% (Ti4O7). The SEM results showed that the morphology of TiO2-BaFe12O19 was quite homogeneous, and the size and cavity ranged from 0.5 – 1.5 μm and 0.25 – 0.9 μm, respectively. VSM results show Mr, Ms, Hc, and Bhmax values of 1,489 kG, 3,235 kG, 1,758 kOe, and Bhmax of 0,867 MGOe, respectively. The results of the Impulse Magnetizer K-Series show the maximum and lowest magnetic flux values of 272.65 gauss and 218.10 gauss at 0.6% and 0% variation, respectively.

Keywords

Barium Ferrite, TiO2, Powder Metallurgy, density, Magnetic Flux

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References

Tazawa T, Yamaguchi H. "Synthesis of identical pole permanent magnet," J. Magn. Magn. Mater., vol. 537, no. May, p. 168180, 2021, doi: 10.1016/j.jmmm.2021.168180. [2] Borges A T, Tecnico C, Gilbert J K. “Models of magnetism,” Int. J. Sci. Educ., vol. 20, no. 3, pp. 361–378, 1998, doi: 10.1080/0950069980200308. [3] Ritawanti A, Sembiring K, Muljadi M, Febrianto E Y. “Pengaruh Ukuran Butir (grain size) pada pembuatan Bonded Magnet NdFeB,” J. Ikat. Alumni Fis., vol. 2, no. 1, p. 10, 2016, doi: 10.24114/jiaf.v2i1.3513. [4] Virdhian S, Wulandari R A, Mu’arif A F, Setiawan A, Sunendar B. “Pengaruh Temperatur dan Waktu Aging pada Sintesis Magnet Nano Barium Heksaferit (BaFe12O19) terhadap Struktur Kristal, Morfologi dan Sifat Magnetik,” Met. Indones., vol. 38, no. 1, p. 1, 2016, doi: 10.32423/jmi.2016.v38.1-7. [5] Kirchmayr H R. “Permanent magnets and hard magnetic materials,” J. Phys. D. Appl. Phys., vol. 29, no. 11, pp. 2763–2778, 1996, doi: 10.1088/0022-3727/29/11/007. [6] Mulyadi M, Djuhana D, Ramlan R. “Komposit Magnet Permanen Berbasis NdFeB –Epoxy Resin dan Karakterisasinya,” Pist. J. Tech. Eng., vol. 2, no. 1, pp. 18–21, 2019, doi: 10.32493/pjte.v2i1.3223. [7] Al Dairy A R, Al-Hmoud L A, Khatatbeh H A. "Magnetic and structural properties of Barium Hexaferrite nanoparticles doped with Titanium," Symmetry (Basel)., vol. 11, no. 6, pp. 1–12, 2019, doi: 10.3390/sym11060732. [8] Pullar R C. "Hexagonal ferrites: A review of the synthesis, properties and applications of hexaferrite ceramics," Prog. Mater. Sci., vol. 57, no. 7, pp. 1191–1334, 2012, doi: 10.1016/j.pmatsci.2012.04.001. [9] Nourbakhsh A A, Noorbakhsh M, Nourbakhsh M, Shaygan M, Mackenzie K J D. "The effect of nano sized SrFe12O19 additions on the magnetic properties of chromium-doped strontium-hexaferrite ceramics," J. Mater. Sci. Mater. Electron., vol. 22, no. 9, pp. 1297–1302, 2011, doi: 10.1007/s10854-011-0303-3. [10] Rizki M, Budiman A, D. Puryanti D. “Barium Ferit ( BaFe12O19) Pasir Besi Batang Sukam Kabupaten Sijunjung Sumatera Barat,” J. Fis. Unand, vol. 7, no. 1, pp. 15–20, 2018. [11] Salam S I, Sanjaya E, Muljadi M. “Pembuatan dan Karakterisasi Keramik Magnet BaFe12O19 dengan Variasi Waktu Milling dan Temperatur Sintering,” Al-Fiziya J. Mater. Sci. Geophys. Instrum. Theor. Phys., vol. 2, no. 1, pp. 29–33, 2019, doi: 10.15408/fiziya.v2i1.10887. [12] Handani S, Mairoza S, Muljadi, “Pembuatan Dan Karakterisasi Magnet Permanen Bao.(6-X)Fe2O3 Dari Bahan Baku Limbah Fe2O3,” J. Ilmu Fis. Univ. Andalas, vol. 3, no. 1, pp. 1–9, 2011, doi: 10.25077/jif.3.1.1-9.2011. [13] Senida Z E, Ramli, Ratnawulan, Hidayati, “Pengaruh Variasi Komposisi MnFe2O4 Terhadap Sifat Magnetik Nanokomposit MnFe2O4/PANi yang Disintesis dengan Metoda Sol-Gel Spin Coating,” Pillar Phys., vol. 12, no. 2, pp. 17–24, 2019. [14] Joni I, Darminto D. “Penerapan Metode Sol-Gel dengan Variasi Temperatur dan Waktu Kalsinasi pada Sintesis Barium M-Heksaferit (BaFe12O19),” J. Fis. dan Apl., vol. 10, no. 1, p. 53, 2014, doi: 10.12962/j24604682.v10i1.827.

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