Sintesis dan Karakterisasi Struktur dan Sifat Magnet Nanokomposit Fe3O4@PEG:ZnO

Abstract

Fe₃O₄@PEG:ZnO nanocomposites were synthesized by the coprecipitation method with various of the samples were Fe₃O₄, Fe₃O₄@ZnO (1:1), Fe₃O₄@PEG: ZnO (1:2), and Fe₃O₄@ PEG: ZnO (1:3). The samples were synthesized with variation in the concentration of ZnO to Fe₃O₄. The concentration ratio of (Fe₃O₄:ZnO) were (1:1), (1:2), and (1:3). In addition, polyethylene glycol (PEG) is also used to prevent the agglomeration of Fe₃O₄. Sample characterization was carried out using X-Ray Diffraction (XRD), Transmission Electron Microscope (TEM), Fourier Transform Infrared (FTIR), Particle Size Analyzer (PSA), and vibrating Sample Magnetometer (VSM). The XRD patterns show that the sample is composed of Fe₃O₄phase and ZnO phase with crystal structure cubic and wurtzite respectively. The TEM image shows the formation of a core-shell structure where PEG: ZnO is the shell and Fe₃O₄ is the core. From the FTIR results, there are C-O and C-C bonds which indicate the formation of PEG, Fe-O bonds indicate the formation of Fe₃O₄ and Zn-O bonds indicate the formation of ZnO. Characterization with PSA obtained particle sizes of 33 nm, 23 nm, and 16 nm with particle size distributions of 25%, 50%, and 75% so that the average particle size is 24 nm. The VSM results show that Fe₃O₄@PEG: ZnO (1:2) nanocomposite has a high magnetic saturation of 66.58 emu/g, with superparamagnetic properties, which has the potential to be developed as a bioimaging material.