Pengaruh Konsentrasi HCl Pada Proses Exfoliasi Graphene Oxide/Reduce Graphene Oxide (GO/rGO) Dari Karbon Bulu Ayam

Erna Hastuti, Feny Fefiyanti, Muthmainnah muthmainnah

Abstract

An increase in the consumption of chicken meat may have an impact on the waste of chicken feathers. Several efforts have been made to treat chicken feather waste, which is difficult to decompose and can pollute the environment. Chicken feathers are biomass with a high keratin content that has the potential to be used as a carbon material. In this study, chicken feathers were used in the chemical exfoliation method to produce reduced Graphene Oxide (rGO) material. Chicken feathers are heated in two stages, at temperatures of 250 and 400 ℃ in the air. The exfoliation procedure was carried out with varying concentrations of HCl (0, 0.5, 1, 1.5, and 2 M). The X-ray diffraction spectra revealed that the sample had a rGO type carbon phase, with the crystal size decreasing as the HCl concentration increased. The presence of functional groups C-O, C=C, and C-OH identified as GO/rGO was revealed by FTIR spectra. The HCl exfoliation process reduced the sample's conductivity and capacitance, with the highest values obtained in aquadest sample (GO-0 M), about 10-5 S/m and 10-7 F/m2.

Keywords

chicken feather, chemical exfoliation, graphene oxide, conductivity, capacitance

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References

  1. Khumalo M, Sithole B, Tesfaye T. 2020 Valorisation of waste chicken feathers: Optimisation of keratin extraction from waste chicken feathers by sodium bisulphite, sodium dodecyl sulphate and urea. Journal of Environmental Management 262, 110329. (doi:10.1016/j.jenvman.2020.110329)
  2. Tuna A, Okumuş Y, Çelebi H, Seyhan AT. 2015 Thermochemical conversion of poultry chicken feather fibers of different colors into microporous fibers. Journal of Analytical and Applied Pyrolysis 115, 112–124. (doi:10.1016/j.jaap.2015.07.008)
  3. Wang Q, Cao Q, Wang X, Jing B, Kuang H, Zhou L. 2013 A high-capacity carbon prepared from renewable chicken feather biopolymer for supercapacitors. Journal of Power Sources 225, 101–107. (doi:10.1016/j.jpowsour.2012.10.022)
  4. Muthukumaraswamy Rangaraj V, Achazhiyath Edathil A, Kadirvelayutham P, Banat F. 2020 Chicken feathers as an intrinsic source to develop ZnS/carbon composite for Li-ion battery anode material. Materials Chemistry and Physics 248, 122953. (doi:10.1016/j.matchemphys.2020.122953)
  5. Ma B, Qiao X, Hou X, Yang Y. 2016 Pure keratin membrane and fibers from chicken feather. International Journal of Biological Macromolecules 89, 614–621. (doi:10.1016/j.ijbiomac.2016.04.039)
  6. Alhamidi AA, Partuti T, Rachmawati D. 2019 Production Of Activated Carbon From Chicken Feather As An Alternative Hydrogen Storage. Journal of Physics: Conference Series 1376, 012034. (doi:10.1088/1742-6596/1376/1/012034)
  7. Alahyaribeik S, Ullah A. 2020 Methods of keratin extraction from poultry feathers and their effects on antioxidant activity of extracted keratin. International Journal of Biological Macromolecules 148, 449–456. (doi:10.1016/j.ijbiomac.2020.01.144)
  8. Hastuti E, Subhan A, Auwala A. 2020 Performance of carbon based on chicken feather with KOH activation as an anode for Li-ion batteries. Materials Today: Proceedings (doi:10.1016/j.matpr.2020.11.429)
  9. Nandi D, Parameswaranpillai J, Siengchin S. 2021 Synthesis of three-dimensional graphene architectures from chicken feather and its unusual dimensional crossover in electronic conductivity. Nano-Structures & Nano-Objects 25, 100665. (doi:10.1016/j.nanoso.2020.100665)
  10. Jaafar E, Kashif M, Sahari SK, Ngaini Z. 2018 Study on Morphological, Optical and Electrical Properties of Graphene Oxide (GO) and Reduced Graphene Oxide (rGO). MSF 917, 112–116. (doi:10.4028/www.scientific.net/MSF.917.112)
  11. Miranda LF, Gomes PVC, de Almeida FJM, Andrade e Silva LG, Munhoz Junior AH, Masson TJ. 2019 Study of the Electrical Properties of rGO Obtained by Different GO Reduction Methods. In Characterization of Minerals, Metals, and Materials 2019 (eds B Li, J Li, S Ikhmayies, M Zhang, YE Kalay, JS Carpenter, J-Y Hwang, SN Monteiro, C Bai, JP Escobedo-Diaz, et al.), pp. 773–785. Cham: Springer International Publishing. (doi:10.1007/978-3-030-05749-7_78)
  12. Gebreegziabher GG, Asemahegne AS, Ayele DW, Dhakshnamoorthy M, Kumar A. 2019 One-step synthesis and characterization of reduced graphene oxide using chemical exfoliation method. Materials Today Chemistry 12, 233–239. (doi:10.1016/j.mtchem.2019.02.003)
  13. Stobinski L, Lesiak B, Malolepszy A, Mazurkiewicz M, Mierzwa B, Zemek J, Jiricek P, Bieloshapka I. 2014 Graphene oxide and reduced graphene oxide studied by the XRD, TEM and electron spectroscopy methods. Journal of Electron Spectroscopy and Related Phenomena 195, 145–154. (doi:10.1016/j.elspec.2014.07.003)
  14. Habte AT, Ayele DW. 2019 Synthesis and Characterization of Reduced Graphene Oxide (rGO) Started from Graphene Oxide (GO) Using the Tour Method with Different Parameters. Advances in Materials Science and Engineering 2019, 1–9. (doi:10.1155/2019/5058163)
  15. Mawhinney DB, Jr JTY. 2001 FTIR study of the oxidation of amorphous carbon by ozone at 300 K — Direct COOH formation. , 7.
  16. Ren X, Li J, Tan X, Wang X. 2013 Comparative study of graphene oxide, activated carbon and carbon nanotubes as adsorbents for copper decontamination. Dalton Trans. 42, 5266. (doi:10.1039/c3dt32969k)
  17. Tran LT, Tran TTT, Le HNT, Nguyen QM, Nguyen MD, Vu THT. In press. Green Synthesis of Reduced Graphene Oxide Nanosheets using Shikimic Acid for Supercapacitors. , 8.
  18. Boychuk VM, Kotsyubynsky VO, Bandura KhV, Yaremiy IP, Fedorchenko SV. 2019 Reduced Graphene Oxide Obtained by Hummers and Marcano-Tour Methods: Comparison of Electrical Properties. j nanosci nanotechnol 19, 7320–7329. (doi:10.1166/jnn.2019.16712)

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