Perolehan Tio2 Dari Iron Ore Mengandung Titanium Melalui Proses Reduksi Karbon Dan Pelarutan Asam

Elda Rayhana, Azwar Manaf

Abstract

REDUCTION AND LEACHING PROCESSES. Indonesia has a large source of iron ore which is quite tempting for the purposes of exploitation in form of raw materials as well as for the production of pig iron. However, not all sources of iron ore are proved useful since not only because the present of deposit is scattere dinamounts of less significant but also because it contains element of tin oxide compounds with iron like ilmenite or FeTiO3. However,ilmenite can actually be used as a source of titanium metal which is much more valuable than Fe it self. In order to recover the Ti from their respective compound it is required the release of strong bonds between the atoms in the compound. This paper reports the recovery of Ti oxide of ilmenite containing iron ore which was obtained through a combination of carbon reduction and acid leaching processes. Carbon reduction of iron ore was carried out through mechanical milling between iron ore and carbon with a ratio of 1:1. This was successively followed by a sintering at a temperature of 1000 oC employing a heating rate of 10 ° C/min for 0-3 hours. The reduction process has resulted in the formation of 27.83wt% TiO2. In order to improve the recovery level of TiO2, further reduction process was conducted through an HCl leaching. This successive stage produced fine powders in the form of deposits. Based on our quantitative analysis, the recovery of TiO2 increased to a level of 73.73%.

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References

Mirko Komatina, Heinrich, W. Gudeau, “ The Sticking Problem During Direct Reduction of Fine Iron Ore in The Fluidized bed” Journal of Metallurgy. 310, 2004

J. F. Gransden, J. S. Sheasby, “ The Sticking of Iron Ore During Reduction by hydrogen in a Fluidized bed”, Can. Metall. Quarterly .13. 649-657,1974

B. Anameric, K.B. Rundman and S.K. Kawatra “Carburization Effects on Pig Iron Nugget

Making” Minerals & Met. Process. Vol. 23.139-150, 2006

4 Constantin C., Mihai T., Dobrescu C., Constantin N, “Reability and Systems Energy Quality Services”Journal of Sustainable Energy Vol. II, NO. 2, 43 - 47, 2011.

Richard S. Treptow, Luckner Jean, The Iron Blast Furnace, A Study in Chemical,“ Hermodyna- mics J.Chem.Educ. 75(1). 43, 1998

Singh, Santokh R and Virdhi P S and Chatterjea,” Production of Molten Pig iron Fine Grained Iron Ore” A B NML Technical Journal, 15 (2). 36-41, 1973

Mehdilo and M. Irannajad,”Applied Mineralogical : Studies on Iranian Hard Rock Titanium Deposi” J. Minerals & Materials Characterization & Engineering, Vol. 9, No.3 (2010) 247-262, 2010

A.F. Buddington, Joseph Fahey, Angelina Vlisidis, “Degree of Oxidation of Adirondack Iron Oxide Minerals in Relation to Petrogeny” Journal of Petrology, Vol. 4, No. 1 138-169, 1963

9 Sadoon Morad, “ Diagenesis of Titani ferrous minerals in Jurassic Sandstone from the Norwegia Sea” Sedimentary Geology, Vol.57. 17 – 40, 1988

10 K.Mondal, H.Lorethova, E. Hippo, J.Wiltowsky, S.B. Lalvani, “Reduction of Iron Oxide in Carbon Monoxide atmosphere-reaction controlled Kinetics” Processing Technology, Vol. 86, 33-37 ,2004

11 M.H.H. Mahmoud, A.A.I. Afifi, I.A. Ibrahim,“Reductive Leaching of ilmenite oer in hydrochloric Acid for Preparation of Rutile” Hydrometallurgy, Vol. 73. 1-2 . 99-109, 2004

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