Characterization of FeMnPO4 as Precursor to LiFeMnPO4: Effect of Reaction pH

Hilmy Naufal Wibowo, Meidiana Arinawati, Khairuddin Khairuddin, Cornelius Satria Yudha

Abstract


The development of the battery market demands batteries with high-performance ability. One of the promising materials to be developed as novel commercial LIBs is Lithium Ferro Manganese Phosphate. Lithium Ferro Manganese Phosphate (LiFe0.5Mn0.5PO4)/LFMP battery can be achieved by preparing the precursors using the co-precipitation method. In this study, the Variation of pH of 2,3, and 4 was used to obtain LFMP precursor Fe0.5Mn0.5PO4while the result was analyzed using characterization techniques. In the FTIR test, there are groups of bending and stretching bonds from H2O, P-O bonds originating from phosphate groups, and Fe-O bonds stretching. In the SEM-EDX test, samples at pH 2 and 3 experienced agglomerations which reduced battery capacity. The percentage of Fe, Mn, P, and O atoms in samples at pH 2 and 3 did not meet stoichiometric calculations due to the side reactions which affected the ratio of Mn and P atoms. In the XRD test, the FeMnPO4 precursor was still in an amorphous phase so it was still difficult to determine the exact crystallization peak. According to the literature. This is partly caused by the temperature and the longtime of stirring. In the TG-DTA test, the pH 2 sample had an initial mass difference of 0.76 grams and underwent an endothermic reaction at a temperature range of 26°- 131°C then took place exothermic in the range of 132-241°C. In the pH 3 sample, an initial mass difference of 1.71 gram and, the exothermic peak was recorded at temperatures of 70.9°C, and 651.88°C. Meanwhile, the endothermic peak was recorded at 701.95°C. The pH 4 sample has a final-initial mass difference of 5.27 grams and the sample undergoes an exothermic reaction in the range of 40-91.73°C and 274.27-297.75°C.


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References


[1] W. Li et al., “Enhancing high-voltage electrochemical performance,” 2020.

[2] C. S. Yudha, A. P. Hutama, M. Rahmawati, and M. Arinawati, “cathode material for high capacity NCA / graphite secondary battery fabrication,” pp. 501–510, 2022.

[3] D. Young, J. Kim, J. Moon, and M. Park, “Off-stoichiometric TiO 2- x -decorated graphite anode for high-power lithium-ion batteries,” Journal of Alloys and Compounds, vol. 843, p. 156042, 2020, doi: 10.1016/j.jallcom.2020.156042.

[4] Q. Cheng, W. M. Chirdon, M. Lin, K. Mishra, and X. Zhou, “Characterization, modeling, and optimization of a single-step process for leaching metallic ions from LiNi 1/3 Co 1/3 Mn 1/3 O 2 cathodes for the recycling of spent lithium-ion batteries,” Hydrometallurgy, vol. 185, pp. 1–11, 2019, doi: 10.1016/j.hydromet.2019.01.003.

[5] M.-K. Tran, A. DaCosta, A. Mevawalla, S. Panchal, and M. Fowler, “Comparative Study of Equivalent Circuit Models Performance in Four Common Lithium-Ion Batteries: LFP, NMC, LMO, NCA,” Batteries, vol. 7, no. 3, p. 51, Jul. 2021, doi: 10.3390/batteries7030051.

[6] Z. Liu et al., “Effects of chelating agents on electrochemical properties of Na0.9Ni0.45Mn0.55O2 cathode materials,” Journal of Alloys and Compounds, vol. 855, p. 157485, 2021, doi: 10.1016/j.jallcom.2020.157485.

[7] J. O. Agunsoye, J. A. Adebisi, S. A. Bello, M. Haris, J. B. Agboola, and S. B. Hassan, “Synthesis of silicon nanoparticles from cassava periderm by reduction method,” Materials Science and Technology 2018, MS and T 2018, no. January, pp. 701–709, 2019, doi: 10.7449/2018/MST_2018_701_709.

[8] J. Yang, B. Guo, H. He, Y. Li, C. Song, and G. Liu, “LiNi0.5Mn0.5O2hierarchical

nanorods as high-capacity cathode materials for Li-ion batteries,” Journal of Alloys and Compounds, vol. 698, pp. 714–718, 2017, doi: 10.1016/j.jallcom.2016.12.264.

[9] W. Zhuang, J. Ye, Z. Song, G. Yin, and G. Li, “Comparison of semi-active hybrid battery system configurations for electric taxis application,” Applied Energy, vol. 259, no. November, p. 114171, 2020, doi: 10.1016/j.apenergy.2019.114171.

[10] R. Aisyah, S. T. Samudera, A. Jumari, and A. Nur, “Synthesis of FePO4 Precursor for LiFePO4 Battery Cathode from Used Nickel Plated A3 Steel Battery Shell by Hydrometallurgy Processing,” Energy Storage Technology and Applications, vol. 1, no. 1, p. 7, 2021, doi: 10.20961/esta.v1i1.56802.

[11] C. Ma, K. Yang, L. Wang, and X. Wang, “Facile synthesis of reduced graphene oxide/Fe3O4 nanocomposite film,” Journal of Applied Biomaterials and Functional Materials, vol. 15, no. Suppl 1, pp. S1–S6, 2017, doi: 10.5301/jabfm.5000341.

[12] M. Arinawati, A. P. Hutama, C. S. Yudha, M. Rahmawati, and A. Purwanto, “Facile rheological route method for LiFePO4/C cathode material production,” Open Engineering, vol. 11, no. 1, pp. 669–676, 2021, doi: 10.1515/eng-2021-0068.

[13] H. M. Barkholtz, A. Fresquez, B. R. Chalamala, and S. R. Ferreira, “A Database for Comparative Electrochemical Performance of Commercial 18650-Format Lithium-Ion Cells,” Journal of The Electrochemical Society, vol. 164, no. 12, pp. A2697–A2706, 2017, doi: 10.1149/2.1701712jes.

[14] B. Sadeghi, R. Sarraf-Mamoory, and H. R. Shahverdi, “Surface modification of LiMn2O4 for lithium batteries by

[1] W. Li et al., “Enhancing high-voltage electrochemical performance,” 2020.

[2] C. S. Yudha, A. P. Hutama, M. Rahmawati, and M. Arinawati, “cathode material for high capacity NCA / graphite secondary battery fabrication,” pp. 501–510, 2022.

[3] D. Young, J. Kim, J. Moon, and M. Park, “Off-stoichiometric TiO 2- x -decorated graphite anode for high-power lithium-ion batteries,” Journal of Alloys and Compounds, vol. 843, p. 156042, 2020, doi: 10.1016/j.jallcom.2020.156042.

[4] Q. Cheng, W. M. Chirdon, M. Lin, K. Mishra, and X. Zhou, “Characterization, modeling, and optimization of a single-step process for leaching metallic ions from LiNi 1/3 Co 1/3 Mn 1/3 O 2 cathodes for the recycling of spent lithium-ion batteries,” Hydrometallurgy, vol. 185, pp. 1–11, 2019, doi: 10.1016/j.hydromet.2019.01.003.

[5] M.-K. Tran, A. DaCosta, A. Mevawalla, S. Panchal, and M. Fowler, “Comparative Study of Equivalent Circuit Models Performance in Four Common Lithium-Ion Batteries: LFP, NMC, LMO, NCA,” Batteries, vol. 7, no. 3, p. 51, Jul. 2021, doi: 10.3390/batteries7030051.

[6] Z. Liu et al., “Effects of chelating agents on electrochemical properties of Na0.9Ni0.45Mn0.55O2 cathode materials,” Journal of Alloys and Compounds, vol. 855, p. 157485, 2021, doi: 10.1016/j.jallcom.2020.157485.

[7] J. O. Agunsoye, J. A. Adebisi, S. A. Bello, M. Haris, J. B. Agboola, and S. B. Hassan, “Synthesis of silicon nanoparticles from cassava periderm by reduction method,” Materials Science and Technology 2018, MS and T 2018, no. January, pp. 701–709, 2019, doi: 10.7449/2018/MST_2018_701_709.

[8] J. Yang, B. Guo, H. He, Y. Li, C. Song, and G. Liu, “LiNi0.5Mn0.5O2hierarchical nanorods as high-capacity cathode materials for Li-ion batteries,” Journal of Alloys and Compounds, vol. 698, pp. 714–718, 2017, doi: 10.1016/j.jallcom.2016.12.264.

[9] W. Zhuang, J. Ye, Z. Song, G. Yin, and G. Li, “Comparison of semi-active hybrid battery system configurations for electric taxis application,” Applied Energy, vol. 259, no. November, p. 114171, 2020, doi: 10.1016/j.apenergy.2019.114171.

[10] R. Aisyah, S. T. Samudera, A. Jumari, and A. Nur, “Synthesis of FePO4 Precursor for LiFePO4 Battery Cathode from Used Nickel Plated A3 Steel Battery Shell by Hydrometallurgy Processing,” Energy Storage Technology and Applications, vol. 1, no. 1, p. 7, 2021, doi: 10.20961/esta.v1i1.56802.

[11] C. Ma, K. Yang, L. Wang, and X. Wang, “Facile synthesis of reduced graphene oxide/Fe3O4 nanocomposite film,” Journal of Applied Biomaterials and Functional Materials, vol. 15, no. Suppl 1, pp. S1–S6, 2017, doi: 10.5301/jabfm.5000341.

[12] M. Arinawati, A. P. Hutama, C. S. Yudha, M. Rahmawati, and A. Purwanto, “Facile rheological route method for LiFePO4/C cathode material production,” Open Engineering, vol. 11, no. 1, pp. 669–676, 2021, doi: 10.1515/eng-2021-0068.

[13] H. M. Barkholtz, A. Fresquez, B. R. Chalamala, and S. R. Ferreira, “A Database for Comparative Electrochemical Performance of Commercial 18650-Format Lithium-Ion Cells,” Journal of The Electrochemical Society, vol. 164, no. 12, pp. A2697–A2706, 2017, doi: 10.1149/2.1701712jes.

[14] B. Sadeghi, R. Sarraf-Mamoory, and H. R. Shahverdi, “Surface modification of LiMn2O4 for lithium batteries by nanostructured LiFePO4 phosphate,” Journal of Nanomaterials, vol. 2012, no. May 2015, 2012, doi: 10.1155/2012/743236.

[15] R. Weber, H. Li, W. Chen, C.-Y. Kim, K. Plucknett, and J. R. Dahn, “ In Situ XRD Studies During Synthesis of Single-Crystal LiNiO 2 , LiNi 0.975 Mg 0.025 O 2 , and LiNi 0.95 Al 0.05 O 2 Cathode Materials ,” Journal of The Electrochemical Society, vol. 167, no. 10, p. 100501, 2020, doi: 10.1149/1945-7111/ab94ef.

[16] X. H. Ma et al., “Three-dimensional MnO/reduced graphite oxide composite films as anode materials for high performance lithium-ion batteries,” Ceramics International, vol. 43, no. 14, pp. 10873–10880, 2017, doi: 10.1016/j.ceramint.2017.05.121.

[17] D. S. Kim, Y. E. Kim, and H. Kim, “Improved fast charging capability of graphite anodes via amorphous Al2O3 coating for high power lithium ion

batteries,” Journal of Power Sources, vol. 422, no. February, pp. 18–24, 2019, doi: 10.1016/j.jpowsour.2019.03.027.

[18] Et. al Sattar, S.R., Ilyas, S., “Recycling of end-of-life LiNixCoyMnzO2 batteries for rare metals recovery,” Environ. Eng. Res., vol. 25, pp. 88–95, 2020.

[19] X. Wang, H. Wang, J. Wen, Y. Tan, and Y. Zeng, “Surface modification of LiMn2O4 cathode with LaCoO3 by a molten salt method for lithium ion batteries,” Ceramics International, vol. 47, no. 5, pp. 6434–6441, 2021, doi: 10.1016/j.ceramint.2020.10.225.

[20] R. Acharya, T. Subbaiah, S. Anand, and R. P. Das, “Preparation, characterization and electrolytic behavior of β-nickel hydroxide,” Journal of Power Sources, vol. 109, no. 2, pp. 494–499, 2002, doi: 10.1016/S0378-7753(02)00164-7.




DOI: https://doi.org/10.20961/esta.v2i2.67675

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