The Effects of Different Nickel–Ruthenium on SiO2 Catalyst Synthesis Methods toward Catalytic Activity of Methane Dry Reforming

Anatta Wahyu Budiman, Nisriina 'Abidah Qurrotul'aini, Nurul Latifah, Puan Hemas Dewani, Shafira Rachmadhani, Sofiana Mukti Wigati

Abstract

The presence of greenhouse gases in the atmosphere has triggered global warming and climate change. An effective approach to overcome these issues is to convert greenhouse gases into syngas. In this study, Ni-Ru/SiO2 catalyst was used to catalyze the dry reforming process of methane (CH4) and carbon dioxide (CO2) into syngas. The catalyst was prepared using different synthesis protocols: sol gel-coprecipitation and impregnation methods. Characterization using Brunauer Emmett Teller analysis showed that the catalyst prepared using both methods exhibited comparable pore diameters and high surface areas. The X-ray diffractometer analysis also indicated the presence of different NiO, RuO2, and SiO2 phases. Furthermore, the activity of the catalyst was investigated using a fixed bed reactor. Based on the results, the optimum catalytic activity was obtained from the catalyst prepared via the sol gel-coprecipitation method, with an average CH4 and CO2 conversions of 37% and 50%, respectively. In addition, our catalyst also showed a 114% higher CH4 conversion with an enhanced H2/CO ratio compared to identical catalysts from other studies.

Full Text:

PDF

References

[1]. R.B. Jackson, M. Saunois, J.G. Canadell, B. Poulter, A.R. Stavert, P. Bergamaschi, P. Bousquet, Y. Niwa, A. Segers, A. Tsuruta, “Increasing Anthropogenic Methane Emissions Arise Equally from Agricultural and Fossil Fuel Sources,” Environ. Res. Lett. 15 1–8 (2020). https://doi.org/10.1088/1748-9326/ab9ed2.

[2]. L. Hockstad, and L. Hanel. (2018). Inventory of U.S. Greenhouse Gas Emissions and Sinks. United States. Available: https://www.osti.gov/dataexplorer/biblio/dataset/1464240 [Accessed: 2 February 2021]

[3]. H.J. Chae, J.H. Kim, S.C. Lee, H.S. Kim, S. Bin Jo, J.H. Ryu, T.Y. Kim, C.H. Lee, S.J. Kim, S.H. Kang, J.C. Kim, M.J. Park, “Catalytic Technologies for CO Hydrogenation for the Production of Light Hydrocarbons and Middle Distillates,” Catalysts. 10 1–32 (2020). https://doi.org/10.3390/catal10010099.

[4]. P. Lu, Q. Huang, A.C. Bourtsalas, Y. Chi, J. Yan, “Effect of Operating Conditions on the Coke Formation and Nickel Catalyst Performance During Cracking of Tar,” Waste and Biomass Valorization. 10 155–165 (2019). https://doi.org/10.1007/s12649-017-0044-5.

[5]. R. Singh, A. Dhir, S.K. Mohapatra, S.K. Mahla, “Dry Reforming of Methane using Various Catalysts in The Process : review,” Biomass Conversion and Biorefinery.10 1–21 (2019).

[6]. A.W. Budiman, S.H. Song, T.S. Chang, M.J. Choi, “Preparation of a High Performance Cobalt Catalyst for CO2 Reforming of Methane,” Adv. Powder Technol. 27 584–590 (2016). https://doi.org/10.1016/j.apt.2016.01.029.

[7]. A.W. Budiman, S.H. Song, T.S. Chang, M.J. Choi, “Preparation of a High Performance Cobalt Catalyst for CO2 Reforming of Methane,” Adv. Powder Technol. 27 584–590 (2016). https://doi.org/10.1016/j.apt.2016.01.029.

[8]. I. Wysocka, J. Hupka, A. Rogala, “Catalytic Activity of Nickel and Ruthenium - Nickel Catalysts Supported on SiO2, ZrO2, Al2O3, and MgAl2O4 in A Dry Reforming Process,” Catalysts. 9 1–13 (2019).

[9]. D. Yao, H. Yang, H. Chen, P.T. Williams, “Co-precipitation, Impregnation and Sol Gel Preparation of Ni Catalysts for Pyrolysis-Catalytic Steam Reforming of Waste Plastics,” Appl. Catal. B Environ. 239 565–577 (2018). https://doi.org/10.1016/j.apcatb.2018.07.075.

[10]. Y. Prasetyaningsih, Hendriyana, H. Susanto, “Influence of impregnation and coprecipitation method in preparation of Cu/ZnO catalyst for methanol synthesis,” J. Eng. Technol. Sci. 48 442–450 (2016). https://doi.org/10.5614/j.eng.technol.sci.2016.48.4.6.

[11]. S. Wang, Z. Tian, Q. Liu, Y. Qiao, Y. Tian, “Facile preparation of a Ni/MgAl2O4 catalyst with high surface area: Enhancement in activity and stability for CO methanation,” Main Gr. Met. Chem. 41 73–89 (2018). https://doi.org/10.1515/mgmc-2018-0003.

[12]. S.S. Itkulova, G.D. Zakumbaeva, A.A. Mukazhanova, Y.Y. Nurmakanov, “Syngas production by biogas reforming over the co-based multicomponent catalysts,” Cent. Eur. J. Chem. 12 1255–1261 (2014). https://doi.org/10.2478/s11532-014-0571-x.

[13]. Y. Liu, W. Sheng, Z. Hou, Y. Zhang, “Homogeneous and highly dispersed ni-ru on a silica support as an effective co methanation catalyst,” RSC Adv. 8 2123–2131 (2018). https://doi.org/10.1039/c7ra13147j.

[14]. C. Yuan, N. Yao, X. Wang, J. Wang, D. Lv, X. Li, “The SiO2 supported bimetallic Ni-Ru particles: A good sulfur-tolerant catalyst for methanation reaction,” Chem. Eng. J. 260 1–10 (2015). https://doi.org/10.1016/j.cej.2014.08.079.

[15]. G. Xiang, V. Alejandro, B. Alicia, B. Roman, H. Jim, L. Wojciech, T. Antonio, “Efficient Ceria Nanostructures for Enhanced Solar Fuel Production via High Temperature Thermochemical Redox Cycles,” J. Mater. Chem. A. 4 9614–9624 (2016).

[16]. M. Heya, X. Gao, A. Tricoli, W. Lipiński, “Effect of specific surface area on syngas production performance of pure ceria in high-temperature thermochemical redox cycling coupled to methane partial oxidation,” RSC Adv. 10 36617–36626 (2020). https://doi.org/10.1039/d0ra06280d.

[17]. J.V. Luke, P. Nicholas, R. Stephen, S. Andreas, H.D. Jane, “The Effect of Morphology on the Oxidation of Ceria by Water and Carbon Dioxied,” J. Sol. Energy Eng. 134 148–162 (2012).

[18]. S. Sadaka, “Gasification, Producer Gas and Syngas,” Agric. Nat. Resour. 15 8 (2017).

[19]. B. Han, L. Zhao, F. Wang, L. Xu, H. Yu, Y. Cui, J. Zhang, W. Shi, “Effect of Calcination Temperature on the Performance of the Ni@SiO2Catalyst in Methane Dry Reforming,” Ind. Eng. Chem. Res. 59 13370–13379 (2020). https://doi.org/10.1021/acs.iecr.0c01213.

[20]. C. Miao, G. Zhou, S. Chen, H. Xie, X. Zhang, “Synergistic effects between Cu and Ni species in NiCu/γ-Al2O3 catalysts for hydrodeoxygenation of methyl laurate,” Renew. Energy. 153 1439–1454 (2020). https://doi.org/10.1016/j.renene.2020.02.099.

[21]. Z. Li, S. Das, P. Hongmanorom, N. Dewangan, M.H. Wai, S. Kawi, “Silica-based micro- and mesoporous catalysts for dry reforming of methane,” Catal. Sci. Technol. 8 2763–2778 (2018). https://doi.org/10.1039/c8cy00622a.

Refbacks

  • There are currently no refbacks.