KINETIKA REAKSI ESTERIFIKASI ASAM FORMIAT DENGAN ETANOL PADA VARIASI SUHU DAN KONSENTRASI KATALIS

Dwi Ardiana Setyawardhani, Yoenitasari Yoenitasari, Sri Wahyuningsih

Abstract

Ethyl Format was produced by esterification between ethanol and formic acid in the presence of sulfuric acid as catalyst. This research studied temperature and catalyst concentration influence to reaction conversion and rate constants. Esterification was done in a laboratory batch reactor with an isothermal and equimolar of reactants conditions. The catalyst concentrations were varied from 0,0923%w/w to 0,9231%w/w and the temperatures were varied from 30oC to 70oC. A quantitative analysis was done by measured the rest of formic acid concentration. The results indicated that the reaction was optimum at 0,3692%w/w sulfuric acid and at the temperature of 50oC. The related equations were given by : k = 6,51.10-3e (-141,9868/RT)* ln Ckatalis with 2,19% errors for the variation of catalyst concentration and k = 3,1143 e (-1079/R)*1/T with 6,52% errors for the temperature variation. By combined all of the datas, an equation which is involved both variables could be given by : k = 6,88.10-3 e-(-100,1965/R) *(ln Ckatalis)/T with 18,29% errors.

Full Text:

PDF

References

Agra, S.W., “Kinetika dan Katalisis : Reaksi Homogen”, bagian 1, pp.2- 5, Fakultas Teknik Universitas Gadjah Mada, Yogyakarta.

Arthur, I., and Vogel, DSc.,1956, “A Text Book of Practical Organic Chemistry Including Qualitative Organic Analysis”, 3rd ed, pp.423,

Longmans Green and Co. Ltd, London. English Jr., J., Cassidy, H.G., and Baird, R.L.,1956, “Principles of Organic Chemistry”, 290, McGraw Hill Book Company, Tokyo.

Fessenden, R.J., dan Fessenden, J.S., 1999, “Kimia Organik”, jilid 2., ed. 3, 83, Erlangga, Jakarta. Fieser, L.F., and Fieser, M., 1957, “Introduction to Organic Chemistry”, pp.131, Maruzen Company Ltd, Tokyo.

frwebgate.acces.gpo.gov/cgi-bin/getcfr.cgi? TITLE = 21 & PART = 184 & SECTION=1295&TYPE=TEXT

Groggins, P.H., 1958, “Unit Processes in Organic Synthesis”, pp.699, McGraw Hill, Inc., New York.

Hill,Jr., C.G., 1977, “An Introduction to Chemical Engineering Kinetics and Reactor Design”, pp.15, John Willey and Sons, New York.

Holum, J.R., 1969, “Principles of Physycal, Organic, and Biological Chemistry”, pp.413., John Willey and Sons, Inc., New York. Keenan, C.W., Kleinfelter, D.C., dan Wood, J.H..,1984, “Kimia untuk Universitas”, jilid 1, ed.6, 521, 522, 594, Erlangga, Jakarta. Kirk, R.E, and Othmer, 1998, “Encyclopedia of Chemical Technology”, 4th ed, 8, 323, John Willey and Sons, New York. Levenspiel, O., 1972, “Chemical Reaction Engineering”, 2nd ed., pp. , 21, 28, 29, John Wiley and Sons, Singapore. Perry, R.H., 1957, “Perry’s “Perrys Chemical Engineers Handbook”, 5 th ed., table 3-206, pp.3-149, McGraw Hill, New York.

Perry, R.H., 1984, “Perry’s Chemical Engineers Handbook”, 7th ed., table 2-109, pp.2-111, McGraw Hill, New York.

Riawan, S., 1987, “Kimia Organik”, ed.1, 153, 180, Binarupa Aksara, Jakarta.

Smith, J.M. and Van Ness, H.C., 1975, “Introduction to Chemical Engineering Thermodynamics”,3rd ed. pp. 386- 389, 410, McGrawHill Int.Inc., Tokyo. Wertheim and Jeskey, 1956, ”Introductory Organic Chemistry”, McGraw Hill, London.

Wood, J.H., Keenan, C.W., and Bull, W.E., 1956, ”Fundamentals of College Chemistry”, pp.223-226, 241, 2nd ed, Harper and Row, New York.

www.cem.msu.edu/- rusch/virtualtext/crbacid1.htm.

http://www.gr.nl/pdf.php?RMATE,+FDA+Pesticide,+OR+flavoring+OR+agent

Yaws, C.W., 1999, “Chemical Properties Handbook”, pp.2-95, McGraw Hill, New York.

DOI: https://doi.org/10.20961/ekuilibrium.v4i2.49602

Refbacks

  • There are currently no refbacks.