Potensi Pemanfaatan Limbah Laundry Sebagai Katoda LiFePO4 Baterai Lithium-ion

Reynaldi Virgiawan Rifki Pradana, Valiana Mugi Rahayu, Yudi Eka Fahroni, Agus Purwanto

Abstract

Tingginya kandungan fosfat dalam limbah laundry sangat berpotensi menimbulkan pencemaran lingkungan, terutama untuk perairan dan tanah. Diperlukan beberapa langkah untuk mengurangi kandungan fosfat dalam limbah laundry, yaitu dengan mengambil atau recovery fosfat. Senyawa hasil dari recovery fosfat salah satunya dapat dimanfaatkan sebagai prekursor Fe dan fosfat dalam sintesis katoda LiFePO4 baterai lithium-ion. Recovery fosfat dari limbah laundry dilakukan menggunakan metode chemical precipitation dengan bantuan senyawa FeCl2.2H2O. Metode kopresipitasi, hidrotermal, dan sol-gel dengan kondisi operasi tertentu dapat dilakukan untuk sintesis LiFePO4 dengan prekursor hasil recovery limbah laundry. Kapasitas yang dihasilkan dari ketiga metode tersebut mendekati kapasitas teoritis LiFePO4 sebesar 170 mAh/g.

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References

Adesoye, A. M., Olayinka, K., Olukomaiya, O. O., & Iwuchukwu, P. O. (2014). The Removal of Phosphates from Laundry Wastewater Using Alum and Ferrous Sulphate as Coagulants. International Journal of Innovation and Scientific Research. 5(October):256–260.

Aulenbach, D. B. (2015). Phosphate Removal from Laundry Wastewater. Journal of Water Pollution Control Federation. 45(8):1708.

Bazzi, K., Nazri, M., Naik, V. M., Garg, V. K., Oliveira, A. C., Vaishnava, P. P., Nazri, G. A., & Naik, R. (2016). Enhancement of Electrochemical Behavior of Nanostructured LiFePO4/Carbon Cathode Material with Excess Li. Journal of Power Sources. 306:17–23.

Cornelissen, E. R., Harmsen, D., Beerendonk, E. F., Qin, J. J., Oo, H., De Korte, K. F., & Kappelhof, J. W. M. N. (2011). The Innovative Osmotic Membrane Bioreactor (OMBR) for Reuse of Wastewater. Water Science and Technology. 63(8):1557–1565.

Feng, H. (2015). A Novel Co-precipitation Method for Carbon-free LiFePO4 and Investigation into Potential LiFePO4-C Cathode Materials for Lithium-ion Batteries. Thesis, Western Sy.

Gao, C., Zhou, J., Liu, G., & Wang, L. (2017). Synthesis of F-doped LiFePO4/C Cathode Materials for High Performance Lithium-ion Batteries using Co-precipitation Method with Hydrofluoric Acid Source. Journal of Alloys and Compounds. 727:501–513.

Guisasola, A., Chan, C., Larriba, O., Lippo, D., Suárez-Ojeda, M. E., & Baeza, J. A. (2019). Long-term Stability of An Enhanced Biological Phosphorus Removal System in A Phosphorus Recovery Scenario. Journal of Cleaner Production. 214:308–318.

Haryono, A., Restu, W. K., & Harmami, S. B. (2012). Preparasi dan Karakterisasi Nanopartikel Aluminum Fosfat. J. Sains Materi Indonesia. 14(1):51–55.

Hou, H., Li, D., Liu, X., Yao, Y., Dai, Z., & Yu, C. (2018). Recovery of Waste Li Foils from Spent Experimental Li-anode Coin Cells for LiFePO4/C Cathode. Sustainable Materials and Technologies. 17:e00064.

Jamarun, N., Sari, T. P., Drajat, S., Azharman, Z., & Asril, A. (2015). Effect of pH Variation on Hydroxyapatite Synthesis Through Sol-gel Method. Research Journal of Pharmaceutical, Biological and Chemical Sciences. 6(3):1065– 1069

Kis, L. T., Albrech, C., & Machado, Ê. L. (2008). Hospital Laundry Wastewater Disinfection with Catalytic Photoozonation. Clean - Soil, Air, Water. 36(9):775.

Li, R. hong, Wang, X. Mao, & Li, X. yan. (2018). A Membrane Bioreactor with Iron Dosing and Acidogenic Co-fermentation for Enhanced Phosphorus Removal and Recovery in Wastewater Treatment. Water Research. 129:402–412.

Mohamed, R. M., Al-Gheethi, A. A., Noramira, J., Chan, C. M., Hashim, M. K. A., & Sabariah, M. (2018). Effect of Detergents from Laundry Greywater on Soil Properties: A Preliminary Study. Applied Water Science. 8(1):1–7.

Omolara Lade, Z. G. (2018). Sustainable water supply: Potential of recycling laundry wastewater for domestic use. Journal of Civil Engineering and Sustainable water supply : Potential of recycling laundry wastewater for domestic use. 4:56–60.

Perera, M. K., Englehardt, J. D., & Dvorak, A. C. (2019). Technologies for Recovering Nutrients from Wastewater: A Critical Review. Environmental Engineering Science. 36(5):511–529.

Prosini, P. P., Cento, C., Masci, A., Carewska, M., & Gislon, P. (2014). A Synthesis of LiFePO4 Starting from FePO4 under Reducing Atmosphere. AIP Conference Proceedings. 1603:109–118.

Qiu, G., & Ting, Y. P. (2014). Direct Phosphorus Recovery from Municipal Wastewater via Osmotic Membrane Bioreactor (OMBR) for Wastewater Treatment. Bioresource Technology. 170:221–229.

Satyavani, T. V. S. L., Kumar, A. S., & Rao, P. S. V. S. (2016). Methods of Synthesis and Performance Improvement of Lithium Iron Phosphate for High Rate Li-ion Batteries: A review. Engineering Science and Technology, an International Journal. 19(1):178–188

Sheth, N., Patel, M., & Desai, M. D. (2017). A Study on Characterization & Treatment of Laundry Effluent. IJIRST-International Journal for Innovative Research in Science & Technology. 4(1):50–55.

Sukačová, K., Trtílek, M., & Rataj, T. (2015). Phosphorus Removal Using A Microalgal Biofilm in A New Biofilm Photobioreactor for Tertiary Wastewater Treatment. Water Research. 71:55–63.

Sun, Y., Zhao, Q., Luo, C., Wang, G., Sun, Y., & Yan, K. (2019). A Novel Strategy for The Synthesis of Fe3(PO4)2 Using Fe-P Waste Slag and CO2 Followed by Its Use as the Precursor for LiFePO4 Preparation. ACS Omega. 4(6):9932–9938.

Toama, H. Z. (2017). World Phosphate Industry. Iraqi Bulletin of Geology and Mining, January 2017. 5–23.

Waluyo, H., & Noerochiem, L, 2014, Pengaruh Temperatur Hydrothermal terhadap Baterai Ion Lithium Type Aqueous Elektrolit, Thesis, Institut Teknologi Sepuluh Nopember, Surabaya.

Yang, M. R., Ke, W. H., & Wu, S. H. (2005). Preparation of LiFePO4 Powders by Co-precipitation. Journal of Power Sources. 146(1–2):539–543.

Ye, Y., Gan, J., & Hu, B. (2015). Screening of Phosphorus-Accumulating Fungi and Their Potential for Phosphorus Removal from Waste Streams. Applied Biochemistry and Biotechnology. 177(5):1127–1136.

Zhao, R. R., Hung, I. M., Li, Y. T., Chen, H. Y., & Lin, C. P. (2012). Synthesis and Properties of Co-doped LiFePO4 as Cathode Material via A Hydrothermal Route for Lithium-ion Batteries. Journal of Alloys and Compounds. 513:282–288.

Zheng, J. C., Li, X. H., Wang, Z. X., Guo, H. J., & Zhou, S. Y. (2008). LiFePO4 with Enhanced Performance Synthesized by A Novel Synthetic Route. Journal of Power Sources. 184(2):574–577.

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