Impact of Nd2O3 on physical properties of lead borate glass system

Ahmad Marzuki, Retno Willy Astuti, Devara Ega Fausta, Fransisca Indraningsih Kasy, Melya Ayu Mahasindi

Abstract

The Nd2O3 doped lead borate glass with composition 45B2O3-(40-x)PbO-11ZnO-4Na2O-xNd2O3 (x=0; 0.5; 1.0; 1.5; 2.0; 2.5) mol% were fabricated using melt quenching method at 950oC for 35 minutes. The characterization of physical properties of glasses doped Nd2O3 were measured by density (ρ) based on the Archimedes principle. The other physical parameters such as molar volume (Vm), oxygen packing density (OPD), polaron radius (rp), ionic radius (ri), field strength (F), molar refraction (Rm), and metallization (Mn) were calculated using equation which derived from density. According to the measurement, the density of glasses decreased from 5.774 to 4.527 gr/cm3 while molar volume oppositely increased from 23.17 to 30.18 cm3/mol due to  atomic mass of Nd (144.24) smaller than Pb (207.2). Along with the increase of molar volume, there were decreasing of the OPD, the polar radius (1.731 －1.095) Å and the ion radius (4.296－2.717) Å iof glasses Meanwhile, the field strength and metallization properties of the glasses  increased as a result of the reduction rp and ri. The investigation of molar refractive shows an increasing trend because the addition of the concentration Nd2O3.

Keywords

Borate glasses, OPD, polaron radius, metalization.

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References

Abdel, B, M., Abdel-Wahab, F. A., & El-Diasty, F. (2012). One-photon band gap engineering of borate glass doped with ZnO for photonics applications. Journal of Applied Physics, 111(7), 073506.

Alazoumi, S. H., Aziz, S. A., El-Mallawany, R., Aliyu, U. S. A., Kamari, H. M., Zaid, M. H. M. M., & Ushah, A. (2018). Optical properties of zinc lead tellurite glasses. Results in Physics, 9, 1371-1376.

Algradee, M. A., Alwany, A. E. B., Sultan, M., Elgoshimy, M., & Almoraisy, Q. (2017). Physical and optical properties for Nd2O3 doped lithium-zinc-phosphate glasses. Optik, 142, 13-22.

Algradee, M. A., Sultan, M., Samir, O. M., & Alwany, A. E. B. (2017). Electronic polarizability, optical basicity and interaction parameter for Nd2O3 doped lithium–zinc–phosphate glasses. Applied Physics A, 123(8), 1-12.

Ali, A. A., & Shaaban, M. H. (2018). Optical and electrical properties of Nd3+ Doped TeBiY borate glasses. Silicon, 10(4), 1503-1511.

Aljewaw, O., Karim, M. K. A., Mohamed Kamari, H., Mohd Zaid, M. H., Mohd Noor, N., Che Isa, I. N., & Abu Mhareb, M. H. (2020). Impact of Dy2O3 substitution on the physical, structural and optical properties of lithium–aluminium–borate glass system. Applied Sciences, 10(22), 8183.

Amer, D., Swapna, K., Kumar, J. S., Mahamuda, S., Venkateswarlu, M., Sruthi, P., & Rao, A. S. (2022). Influence of Sm3+ ion concentration on the photoluminescence behavior of antimony lead oxy fluoro borate glasses. Materials Research Bulletin, 146, 111597.

Annapoorani, K., Murthy, N. S., Ravindran, T. R., & Marimuthu, K. (2016). Influence of Er3+ ion concentration on spectroscopic properties and luminescence behavior in Er3+ doped Strontium

Chen, Qiuping & Ferraris, Monica & Menke-Berg, Yvonne & Milanese, Daniel & Monchiero, Elena. (2003). Novel erbium doped PbO and B2O3 based glasses with broad 1.5 μm absorption line width and low refractive index. Journal of Non-Crystalline Solids. 324. 1-11.

Dumbaugh, William & Lapp, Josef. (2005). Heavy‐Metal Oxide Glasses. Journal of the American Ceramic Society. 75. 2315 - 2326.

Elkhoshkhany, N., Marzouk, S., El-Sherbiny, M., & Ahmed, A. (2019). Properties of tellurite glass doped with ytterbium oxide for optical applications. Journal of Materials Science: Materials in Electronics, 30(7), 6963-6976.

Elsad, R. A., Abdel-Aziz, A. M., Ahmed, E. M., Rammah, Y. S., El-Agawany, F. I., & Shams, M. S. (2021). FT-IR, ultrasonic and dielectric characteristics of neodymium (III)/erbium (III) lead-borate glasses: experimental studies. Journal Of Materials Research And Technology, 13, 1363-1373

Fausta, Devara & Marzuki, Ahmad & Cari,. (2020). Infrared absorption spectra analysis of TeO 2 -ZnO-Bi 2 O 3 -TiO 2 doped B2O3 glasses. Journal of Physics: Conference Series. 1511. 012076.

Halimah, M. K., Awshah, A. A., Hamza, A. M., Chan, K. T., Umar, S. A., & Alazoumi, S. H. (2020). Effect of neodymium nanoparticles on optical properties of zinc tellurite glass system. Journal of Materials Science: Materials in Electronics, 31(5), 3785-3794.

Hu, Z, Q & Zhang, H, F. (2017). in Modern Inorganic Synthetic Chemistry (Second Edition).

James, J. T., Jose, J. K., Manjunatha, M., Suresh, K., & Madhu, A. (2020). Structural, luminescence and NMR studies on Nd3+-doped sodium–calcium-borate glasses for lasing applications. Ceramics International, 46(17), 27099-27109.

Kaur, S., Mohan, S., & Singh, D. P. (2021). Spectroscopic properties and lasing potentialities of Sm3+ doped multi-component borate glasses. Optics Communications, 482, 126523.

Mahamuda, S., Swapna, K., Rao, A. S., Jayasimhadri, M., Sasikala, T., Pavani, K., & Moorthy, L. R. (2013). Spectroscopic properties and luminescence behavior of Nd3+ doped zinc alumino bismuth borate glasses. Journal of Physics and Chemistry of Solids, 74(9), 1308-1315.

Marzuki, Ahmad & Djeksadipura, Widoastiningrum & Suryanti, Venty & Fausta, Devara & Saraswati, Azmi & Singgih, G. (2021). Compositional dependence of density and refractive index in borotellurite glass. Journal of Physics: Conference Series. 1912. 012026.

Mhareb, M. H. A., Hashim, S., Ghoshal, S. K., Alajerami, Y. S. M., Saleh, M. A., Dawaud, R. S., & Azizan, S. A. B. (2014). Impact of Nd3+ ions on physical and optical properties of Lithium Magnesium Borate glass. Optical Materials, 37, 391-397.

Nasuha, M. R. S., Azhan, H., Hasnimulyati, L., Razali, W. A. W., & Norihan, Y. (2021). Effect of Nd3+ ions on physical and optical properties of yttrium lead borotellurite glass system. Journal of Non-Crystalline Solids, 551, 120463.

Nor, R. M., Halim, S. M., Taib, M. F. M., Ibrahim, A. B., & Abd-Rahman, M. K. (2017). First principles study on phonon energy in SiO2 glass with the incorporation of Al2O3. In Solid State Phenomena (Vol. 268, pp. 160-164). Trans Tech Publications Ltd.

Rajaramakrishna, R., & Kaewkhao, J. (2021). Laser medium from glass material. SIAM: Science and Innovation of Advanced Materials, 1(1), 64003-64003.

Razali, W. A. W., Azman, K., Ridzwan, H. J. M., Azhan, H., Senawi, S. A., Sahar, M. R., & Rohani, M. S. (2012). Effect of Li2O on the physical properties of Nd2O3 doped tellurite glass. Solid State Sci. Technol., 20, 121-127.

Saraswati, A & Marzuki, Ahmad & Fausta, Devara & Suryanti, Venty & Singgih, G. (2021). Borate Glasses for Low Loss Optical Fibre. Journal of Physics: Conference Series. 1912. 012006.

Wagh, A., Raviprakash, Y., Upadhyaya, V., & Kamath, S. D. (2015). Composition dependent structural and optical properties of PbF2–TeO2–B2O3–Eu2O3 glasses. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 151, 696-706.

Wu, J., & Stebbins, J. F. (2014). Cation field strength effects on boron coordination in binary borate glasses. Journal of the American Ceramic Society, 97(9), 2794-2801.

DOI: https://doi.org/10.20961/jphystheor-appl.v7i2.71762

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