Precursor concentration effect on optical properties of carbon dots from Cassava’s peels

Permono Adi Putro, Liszulfah Roza, Isnaeni Isnaeni

Abstract

Carbon dots (C-dots) are a new type of fluorescent nanoparticles that can be readily synthesized from natural sources, such as cassava’s peels. In this work, C-dots were synthesized from cassava’s peels using low temperature green synthesis based. The Green synthesis techniques were done by using water as a solvent non-chemical and natural sources. The Synthesis was done using various concentrations of precursor from 0.25%, 0.50%, 1.0% and 2.0%. Optical properties of C-dots were characterized using spectrophotometer UV-Vis, photoluminescence (PL) and time resolved photoluminescence (TRPL). The concentration of precursor lead to differences in molecular density and content of preparation thus affecting optical properties. The performance of C-dots optical properties were dominated by the transition of electrons n–π* on structure aromtic C=O which originate from the surface of C-dots. The result of C-dots sample with a concentration of 2.0% precursors has the best emission effiency. This provides the potential for C-dots cassava’s peels in the aqueous solution to be applied as cellular bioimaging and biosensing metal ions and salts.

Keywords

C-dots, concentration of precursor, optical properties

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References

Asha Jhonsi, M., & Kathiravan, A. (2017). Photoinduced interaction of arylamine dye with carbon quantum dots ensued from centella asiatica. Journal of Luminescence, 192, 321–327. https://doi.org/10.1016/j.jlumin.2017.06.056

Baker, S. N., & Baker, G. A. (2010). Luminescent carbon nanodots: Emergent nanolights. Angewandte Chemie - International Edition, 49(38), 6726–6744. https://doi.org/10.1002/anie.200906623

Dimos, K. (2016). Carbon quantum dots: Surface passivation and functionalization. Current Organic Chemistry, 20, 682–695. https://doi.org/10.2174/1385272819666150730220948

Ding, H., Yu, S. B., Wei, J. S., & Xiong, H. M. (2016). Full-color light-emitting carbon dots with a surface-state-controlled luminescence mechanism. ACS Nano, 10(1), 484–491. https://doi.org/10.1021/acsnano.5b05406

Fatimah, S., Isnaeni, & Tahir, D. (2018). Assisted surface-state recombination of orange-peel carbon nanodots in various matrices. Makara J. Sci, 22(1), 29–34. https://doi.org/10.7454/mss.v22.i1.8301

Goryacheva, I. Y., Sapelkin, A. V., & Sukhorukov, G. B. (2017). Carbon nanodots: Mechanisms of photoluminescence and principles of application. TrAC - Trends in Analytical Chemistry, 90, 27–37. https://doi.org/10.1016/j.trac.2017.02.012

Han, S., Chang, T., Zhao, H., Du, H., Liu, S., Wu, B., & Qin, S. (2017). Cultivating fluorescent flowers with highly luminescent carbon dots fabricated by a double passivation method. Nanomaterials, 7(7), 176. https://doi.org/10.3390/nano7070176

Hassan, M., Gomes, V. G., Dehghani, A., & Ardekani, S. M. (2018). Engineering carbon quantum dots for photomediated theranostics. Nano Research, 11(1), 1–41. https://doi.org/10.1007/s12274-017-1616-1

Hola, K., Zhang, Y., Wang, Y., Giannelis, E. P., Zboril, R., & Rogach, A. L. (2014). Carbon dots-Emerging light emitters for bioimaging, cancer therapy and optoelectronics. Nano Today, 9(5), 590–603. https://doi.org/10.1016/j.nantod.2014.09.004

Hu, Q., Gong, X., Liu, L., & Choi, M. M. F. (2017). Characterization and analytical separation of fluorescent carbon nanodots. Journal of Nanomaterials, 30–37. https://doi.org/10.1155/2017/1804178

Huang, H., Lv, J. J., Zhou, D. L., Bao, N., Xu, Y., Wang, A. J., & Feng, J. J. (2013). One-pot green synthesis of nitrogen-doped carbon nanoparticles as fluorescent probes for mercury ions. RSC Advances, 3(44), 21691–21696. https://doi.org/10.1039/c3ra43452d

Isnaeni, Hanna, M. Y., Pambudi, A. A., & Murdaka, F. H. (2017). Influence of ablation wavelength and time on optical properties of laser ablated carbon dots. AIP Conference Proceedings, 1801(020001), 1–5. https://doi.org/10.1063/1.4973079

Isnaeni, Rahmawati, I., Intan, R., & Zakaria, M. (2018). Photoluminescence study of carbon dots from ginger and galangal herbs using microwave technique. Journal of Physics: Conf. Series, (985), 1–6. https://doi.org/10.1088/1742-6596/985/1/012004

Jaleel, J. A., & Pramod, K. (2018). Artful and multifaceted applications of carbon dot in biomedicine. Journal of Controlled Release, 269, 302–321. https://doi.org/10.1016/j.jconrel.2017.11.027

Li, Q., Zhou, M., Yang, M., Yang, Q., Zhang, Z., & Shi, J. (2018). Induction of long-lived room temperature phosphorescence of carbon dots by water in hydrogen-bonded matrices. Nature Communications, 9(734), 1–8. https://doi.org/10.1038/s41467-018-03144-9

Liu, Y., Zhao, Y., & Zhang, Y. (2014). One-step green synthesized fluorescent carbon nanodots from bamboo leaves for copper (II) ion detection. Sensors and Actuators, B: Chemical, 196, 647–652. https://doi.org/10.1016/j.snb.2014.02.053

Ma, X., Dong, Y., Sun, H., & Chen, N. (2017). Highly fluorescent carbon dots from peanut shells as potential probes for copper ion: The optimization and analysis of the synthetic process. Materials Today Chemistry, 5, 1–10. https://doi.org/10.1016/j.mtchem.2017.04.004

Mazrad, Z. A. I., Kang, E. B., In, I., & Park, S. Y. (2018). Preparation of carbon dot-based ratiometric fluorescent probes for cellular imaging from curcuma longa. Luminescence, 33(1), 40–46. https://doi.org/10.1002/bio.3370

Morita, K., Kurusu, S., Kodama, H., & Hirayama, N. (2017). Effect of the elemental composition of precursors from amino acids and their binary mixtures on the photoluminescent intensity of carbon nanodots. Analytical Sciences, 33, 1461–1464. https://doi.org/10.2116/analsci.33.1461

Neto, A. H. C., Guinea, F., Peres, N. M. R., Novoselov, K. S., & Geim, A. K. (2009). The electronic properties of graphene. Reviews of Modern Physics, 81, 109–162. https://doi.org/10.1103/RevModPhys.81.109

Ngu, P. Z. Z., Chia, S. P. P., Fong, J. F. Y., & Ng, S. M. (2016). Synthesis of carbon nanoparticles from waste rice husk used for the optical sensing of metal ions. New Carbon Materials, 31(2), 135–143. https://doi.org/10.1016/S1872-5805(16)60008-2

Shen, J., Shang, S., Chen, X., Wang, D., & Cai, Y. (2017). Facile synthesis of fluorescence carbon dots from sweet potato for Fe3+ sensing and cell imaging. Materials Science and Engineering C, 76, 856–864. https://doi.org/10.1016/j.msec.2017.03.178

Varisco, M., Zufferey, D., Ruggi, A., Zhang, Y., Erni, R., & Mamula, O. (2017). Synthesis of hydrophilic and hydrophobic carbon quantum dots from waste of wine fermentation. Royal Society Open Science, 4(12), 170900. https://doi.org/10.1098/rsos.170900

Wang, C., Xu, Z., & Zhang, C. (2015). Polyethyleneimine-functionalized fluorescent carbon dots: Water stability, pH sensing, and cellular imaging. ChemNanoMat, 1(2), 122–127. https://doi.org/10.1002/cnma.201500009

Wang, R., Lu, K.-Q., Tang, Z.-R., & Xu, Y.-J. (2017). Recent progress in carbon quantum dots: synthesis, properties and applications in photocatalysis. J. Mater. Chem. A, 5(8), 3717–3734. https://doi.org/10.1039/C6TA08660H

Yin, B., Deng, J., Peng, X., Long, Q., Zhao, J., Lu, Q., … Yao, S. (2013). Green synthesis of carbon dots with down- and up-conversion fluorescent properties for sensitive detection of hypochlorite with a dual-readout assay. Analyst, 138(21), 6551–6557. https://doi.org/10.1039/c3an01003a

Yoshinaga, T., Iso, Y., & Isobe, T. (2018). Particulate, structural, and optical properties of D-glucose-derived carbon dots synthesized by microwave-assisted hydrothermal treatment. ECS Journal of Solid State Science and Technology, 7(1), R3034–R3039. https://doi.org/10.1149/2.0091801jss

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