Comparative Study of Novelty Thin-films for Li-ion Batteries
Abstract
The development of Li-ion batteries leads to high-density Li-ion battery technology as a storage system. to realize a Li-ion battery with a high energy density is to modify its anode, called a thin-film anode. The anode used is coated with a material thickness of 10 mm, increasing the cathode material that can be accommodated in one cell. This study aimed to analyze the Cu-powder and LTO materials used in Thin-film Li-ion batteries as a substitute for graphite because they offer higher capacity, chemical stability, fast charging technology (LTO), cheap, and environmentally friendly (Cu-powder). Based on XRD and FTIR tests, the material has a good crystal structure, and not many impurities are still contained in it. The SEM results showed that both particles showed uniformity in the shape of a single particle and were strengthened by the SEM-EDX test to review the quantity of each element present in the two materials. The electrochemical test results showed that Cu-powder material was better, with a specific capacity of 144.82 mAh g-1, higher than LTO (81.04 mAh g-1).
Full Text:
PDFReferences
S. Chu, Y. Cui, and N. Liu, “The path towards sustainable energy,” Nature Materials, vol. 16, no. 1, pp. 16–22, 2016, DOI: 10.1038/nmat4834.
Y. Qiao, H. Yang, Z. Chang, H. Deng, X. Li, and H. Zhou, “A high-energy-density and long-life initial-anode-free lithium battery enabled by a Li2O sacrificial agent,” Nature Energy, vol. 6, no. 6, pp. 653–662, 2021, DOI: 10.1038/s41560-021-00839-0.
J. B. Goodenough and K. S. Park, “The Li-ion rechargeable battery: A perspective,” J Am Chem Soc, vol. 135, no. 4, pp. 1167–1176, 2013, DOI: 10.1021/ja3091438.
D. Deng, “Li-ion batteries: Basics, progress, and challenges,” Energy Science and Engineering, vol. 3, no. 5. John Wiley and Sons Ltd, pp. 385–418, Sep. 01, 2015. DOI: 10.1002/ese3.95.
Q. Li et al., “Homogeneous Interface Conductivity for Lithium Dendrite-Free Anode,” ACS Energy Letters, vol. 3, no. 9, pp. 2259–2266, 2018, doi: 10.1021/acsenergylett.8b01244.
N. Nitta, F. Wu, J. T. Lee, and G. Yushin, “Li-ion battery materials : present and future,” Biochemical Pharmacology, vol. 18, no. 5, pp. 252–264, 2015, DOI: 10.1016/j.mattod.2014.10.040.
R. Li, W. Yue, and X. Chen, “Fabrication of porous carbon-coated ZnO nanoparticles on electrochemical exfoliated graphene as an anode material for lithium-ion batteries,” Journal of Alloys and Compounds, vol. 784, pp. 800–806, May 2019, DOI: 10.1016/j.jallcom.2019.01.117.
J. Ginting, E. Yulianti, and Sudaryanto, “SINTESIS Li2TiO3 SEBAGAI BAHAN ANODA BATERAI Li-ION DENGAN METODE REAKSI PADATAN,” Jurnal Sains Materi Indonesia, vol. 15, 2014.
Z. Zhang, Y. Wang, J. Hu, Q. Wu, and Q. Zhang, “Influence of mixing method and hydraulic retention time on hydrogen production through photo-fermentation with mixed strains,” International Journal of Hydrogen Energy, vol. 40, no. 20, pp. 6521–6529, 2015, DOI: 10.1016/j.ijhydene.2015.03.118.
W. Xu et al., “Lithium metal anodes for rechargeable batteries,” Energy and Environmental Science, vol. 7, no. 2, pp. 513–537, 2014, DOI: 10.1039/c3ee40795k.
R. Dang, X. Jia, X. Liu, H. Ma, H. Gao, and G. Wang, “Controlled synthesis of hierarchical Cu nanosheets @ CuO nanorods as high-performance anode material for lithium-ion batteries,” Nano Energy, vol. 33, pp. 427–435, 2017, DOI: 10.1016/j.nanoen.2017.01.024.
S. H. Lee, Y. Noh, Y. R. Jo, Y. Kim, B. J. Kim, and W. B. Kim, “Carbon-Encapsulated SnO2 Core–Shell Nanowires Directly Grown on Reduced Graphene Oxide Sheets for High-Performance Li-Ion Battery Electrodes,” Energy Technology, vol. 6, no. 7, pp. 1255–1260, 2018, DOI: 10.1002/ente.201700804.
L. Lu, Y. Hu, and K. Dai, “The advance of fiber-shaped lithium-ion batteries,” Materials Today Chemistry, vol. 5, pp. 24–33, 2017, DOI: 10.1016/j.mtchem.2017.05.003.
M. Odziomek et al., “Hierarchically structured lithium titanate for ultrafast charging in long-life high capacity batteries,” Nature Communications, vol. 8, no. May, pp. 1–7, 2017, DOI: 10.1038/ncomms15636.
A. Purwanto et al., “High performance of salt-modified–to the anode in lifepo4 battery,” Applied Sciences (Switzerland), vol. 10, no. 20, pp. 1–15, 2020, DOI: 10.3390/app10207135.
S. Y. Yin et al., “Molten salt synthesis of sodium lithium titanium oxide anode material for lithium-ion batteries,” Journal of Alloys and Compounds, vol. 642, pp. 1–6, 2015, DOI: 10.1016/j.jallcom.2015.04.113.
Y. Sha, B. Zhao, R. Ran, R. Cai, and Z. Shao, “Synthesis of well-crystallized Li4Ti5O12 nanoplates for lithium-ion batteries with outstanding rate capability and cycling stability,” Journal of Materials Chemistry A, vol. 1, no. 42, pp. 13233–13243, 2013, DOI: 10.1039/c3ta12620j.
Y. Chu, M. Chen, S. Chen, B. Wang, K. Fu, and H. Chen, “Micro-copper powders recovered from waste printed circuit boards by electrolysis,” Hydrometallurgy, vol. 156, pp. 152–157, Jun. 2015, DOI: 10.1016/j.hydromet.2015.06.006.
J. Temuujin et al., “Preparation of copper and silicon/copper powders by a gas evaporation-condensation method,” Bulletin of Materials Science, vol. 32, no. 5, pp. 543–547, Nov. 2009, DOI: 10.1007/s12034-009-0081-1.
P. Hosseini, “Comparative study between Li4Ti5O12 and Pr doped Li4Ti5O12 in Li-Sulfur battery with Li2S cathodic electrode,” 2017. [Online]. Available: https://www.researchgate.net/publication/321801918
B. Vikram Babu et al., “Structural and electrical properties of Li4Ti5O12 anode material for lithium-ion batteries,” Results in Physics, vol. 9, pp. 284–289, Jun. 2018, DOI: 10.1016/j.rinp.2018.02.050.
S. Priyono, B. M. Lubis, S. Humaidi, and B. Prihandoko, “Heating Effect on Manufacturing Li4Ti5O12 Electrode Sheet with PTFE Binder on Battery Cell Performance,” in IOP Conference Series: Materials Science and Engineering, Jun. 2018, vol. 367, no. 1. doi: 10.1088/1757-899X/367/1/012007.
R. Betancourt-Galindo et al., “Synthesis of Copper Nanoparticles by Thermal Decomposition and Their Antimicrobial Properties,” Article in Nanomaterials, vol. 2013, 2013, DOI: 10.1155/2013/980545.
Z. Janković, M. M. Pavlović, M. R. P. Pavlović, N. D. Nikolić, V. Zečević, and M. G. Pavlović, “Electrical conductivity of poly (L lactic acid) and poly (3-hydroxybutyrate) composites filled with galvanostatically produced copper powder,” Hemijska Industrija, vol. 72, no. 5, pp. 285–292, 2018, DOI: 10.2298/HEMIND180530020J.
N. B. Tanvir, O. Yurchenko, C. Wilbertz, and G. Urban, “Investigation of CO2 reaction with copper oxide nanoparticles for room temperature gas sensing,” Journal of Materials Chemistry A, vol. 4, no. 14, pp. 5294–5302, 2016, DOI: 10.1039/c5ta09089j.
M. Moyo, G. Nyamhere, E. Sebata, and U. Guyo, “Kinetic and equilibrium modeling of lead sorption from aqueous solution by activated carbon from goat dung,” Desalination and Water Treatment, vol. 57, no. 2, pp. 765–775, Jan. 2016, DOI: 10.1080/19443994.2014.968217.
C. K. Lan, C. C. Chang, C. Y. Wu, B. H. Chen, and J. G. Duh, “Improvement of the Ar/N2 binary plasma-treated carbon passivation layer deposited on Li4Ti5O12 electrodes for stable high-rate lithium-ion batteries,” RSC Advances, vol. 5, no. 112, pp. 92554–92563, 2015, DOI: 10.1039/c5ra17522d.
J. Gao, B. Gong, Q. Zhang, G. Wang, Y. Dai, and W. Fan, “Study of the surface reaction mechanism of Li4Ti5O12 anode for lithium-ion cells,” Ionics (Kiel), vol. 21, no. 9, pp. 2409–2416, Sep. 2015, DOI: 10.1007/s11581-015-1435-x.
DOI: https://doi.org/10.20961/esta.v2i1.61268
Refbacks
- There are currently no refbacks.